Tris(3,3′,3″-phosphinidynetris(benzenesulfonato)palladium(0) nonasodium salt nonahydrate

产品名称：

176483-72-0
Tris(3,3′,3″-phosphinidynetris(benzenesulfonato)palladium(0) nonasodium salt nonahydrate
三(3,3′,3″-次膦基三(苯磺酸基)钯(0) 九钠盐九水合物

产品介绍：

产品说明

应用

Tris(3,3′,3″-phosphinidynetris(benzenesulfonato)palladium(0) nonasodium salt nonahydrate (Pd-TPPTS complex) supported by layered double hydroxide (LDH) can be used as an efficient catalyst in the cycloisomerization of acetylenic carboxylic acids to the corresponding 5-membered heterocycles.

包装

500 mg in glass bottle

基本信息

线性分子式	Pd(P(C₆H₄SO₃·Na)₃)₃ · 9H₂O
分子量	1982.89
MDL编号	MFCD08457632
PubChem化学物质编号	24880354
NACRES	NA.22

产品性质

reaction suitability	core: palladium reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: catalyst
质量水平	100
mp	>300 ℃ (lit.)
储存温度	2-8℃
SMILES string	[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Pd].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[O-]S(=O)(=O)c1cccc(c1)P(c2cccc(c2)S([O-])(=O)=O)c3cccc(c3)S([O-])(=O)=O.[O-]S(=O)(=O)c4cccc(c4)P(c5cccc(c5)S([O-])(=O)=O)c6cccc(c6)S([O-])(=O)=O.[O-]S(=O)(=O)c7cccc(c7)P(c8cccc(c8)S([O-])(=O)=O)c9cccc(c9)S([O-])(=O)=O
InChI	1S/3C18H15O9PS3.9Na.9H2O.Pd/c319-29(20,21)16-7-1-4-13(10-16)28(14-5-2-8-17(11-14)30(22,23)24)15-6-3-9-18(12-15)31(25,26)27;;;;;;;;;;;;;;;;;;;/h31-12H,(H,19,20,21)(H,22,23,24)(H,25,26,27);;;;;;;;;;91H2;/q;;;9+1;;;;;;;;;;/p-9
InChI key	RZJLWYKBARRAJM-UHFFFAOYSA-E

安全信息

储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Gloves, type N95 (US)