产品说明
应用
Methyl α-bromoacrylate can undergo radical copolymerization with vinyl triacetoxysilane (VTAS) in the presence of azobisisobutyronitrile as the initiator. Dibromocyclopropanation of methyl α-bromoacrylate can yield methyl 1,1,2-tribromocyclopropanecarboxylate. It may be reduced with zinc dust and deuterium oxide to synthesize. Methyl acrylate-α-d with a high isotopic purity. These may undergo conjugate addition with methoxide, thiolates, oxime anions, hydrazones and EtZnCl to afford ester enolates.
包装
1 g in glass insert
基本信息
| 经验(实验)分子式 | C4H5BrO2 |
| 分子量 | 164.99 |
| MDL编号 | MFCD08276754 |
| PubChem化学物质编号 | 24881219 |
| NACRES | NA.23 |
产品性质
| 质量水平 | 100 |
| 测定 | 95% |
| bp | 70-75 ℃/48 mmHg (lit.) |
| 密度 | 1.556 g/mL at 25 ℃ (lit.) |
| 储存温度 | −20℃ |
| SMILES string | COC(=O)C(Br)=C |
| InChI | 1S/C4H5BrO2/c1-3(5)4(6)7-2/h1H2,2H3 |
| InChI key | HVJXPDPGPORYKY-UHFFFAOYSA-N |
安全信息
| 象形图 |   |
| 警示用语： | Warning |
| 危险声明 | H226 - H315 - H319 - H335 |
| 预防措施声明 | P210 - P302 + P352 - P305 + P351 + P338 |
| 危险分类 | Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3 |
| 靶器官 | Respiratory system |
| 储存分类代码 | 3 - Flammable liquids |
| WGK | WGK 3 |
| 闪点(F) | 134.6 °F - closed cup |
| 闪点(C) | 57 ℃ - closed cup |
| 个人防护装备 | Eyeshields, Gloves, type ABEK (EN14387) respirator filter |
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