产品说明
应用
Unnatural amino acid was derived from a C-H Activation methodology developed by Jin-Quan Yu and coworkers. The Pd-mediated C-C bond formation can be made in tandem with 2-Methylpyridine (Aldrich 109835).
包装
1 g in glass bottle
其他说明
Ligand-Controlled C(sp3)–H Arylation and Olefination in Synthesis of Unnatural Chiral α–Amino Acids
基本信息
经验(实验)分子式 | C16H17F6NO4 |
分子量 | 401.30 |
PubChem化学物质编号 | 329772653 |
NACRES | NA.22 |
产品性质
质量水平 | 100 |
描述 | ALPH: +24.0, 0.5%EtOH |
测定 | ≥95% (HPLC) |
形式 | powder or solid |
reaction suitability | reaction type: Boc solid-phase peptide synthesis reagent type: ligand reaction type: C-H Activation |
application(s) | peptide synthesis |
储存温度 | 2-8℃ |
SMILES string | OC([C@@H](NC(OC(C)(C)C)=O)CC1=CC(C(F)(F)F)=C(C(F)(F)F)C=C1)=O |
InChI | 1S/C16H17F6NO4/c1-14(2,3)27-13(26)23-11(12(24)25)7-8-4-5-9(15(17,18)19)10(6-8)16(20,21)22/h4-6,11H,7H2,1-3H3,(H,23,26)(H,24,25)/t11-/m0/s1 |
InChI key | LLRXWQAYIGATCH-NSHDSACASA-N |
安全信息
象形图 | |
警示用语: | Warning |
危险声明 | H315 - H319 - H335 |
预防措施声明 | P302 + P352 - P305 + P351 + P338 |
危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
靶器官 | Respiratory system |
储存分类代码 | 11 - Combustible Solids |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |
Sigma-Aldrich