产品名称：
37031-30-4
(+)-Dimethyl 2,3-O-isopropylidene-D-tartrate
(4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-dicarboxylic acid dimethyl ester
Dimethyl (4S,5S)-2,2-dimethyl-1,3-dioxolane-4,5-dicarboxylate
(+)-二甲基 2,3-O-异亚丙基-D-酒石酸酯
二甲基 (4S,5S)-2,2-二甲基-1,3-二氧戊环-4,5-二羧酸酯
(4S,5S)-2,2-二甲基-1,3-二氧戊环-4,5-二羧酸二甲酯
产品介绍：
产品说明
一般描述
(+)-Dimethyl 2,3-O-isopropylidene-D-tartrate is a chiral reagent used in organic synthesis. It is prepared by the reaction-rectification process from D -tartrate, and 2,2-dimethoxypropane.{138]
应用
TADDOL 手性助剂、联吡啶配体和苏糖醇的有用结构单元。
(+)-Dimethyl 2,3-O-isopropylidene-D-tartrate can be used as a starting material for the synthesis of:
- Deuterated 1-deoxy-D-xylose.
- C-terminal peptide -oxo-aldehydes using Fmoc solid-phase peptide synthesis methodology (SPPS).
- Bis-Weinreb amide, a key intermediate for the preparation of myo-inositol analog via ring-closing metathesis.
包装
5 g in glass bottle
基本信息
| 经验(实验)分子式 | C9H14O6 |
| 分子量 | 218.20 |
| Beilstein | 3548490 |
| MDL编号 | MFCD00040504 |
| PubChem化学物质编号 | 24863661 |
| NACRES | NA.22 |
产品性质
| 质量水平 | 100 |
| 测定 | 98% |
| 旋光性 | [α]20/D +54°, neat |
| 折射率 | n20/D 1.439 (lit.) |
| bp | 80-82 ℃/0.1 mmHg (lit.) |
| 密度 | 1.19 g/mL at 25 ℃ (lit.) |
| SMILES string | COC(=O)[C@H]1OC(C)(C)O[C@@H]1C(=O)OC |
| InChI | 1S/C9H14O6/c1-9(2)14-5(7(10)12-3)6(15-9)8(11)13-4/h5-6H,1-4H3/t5-,6-/m0/s1 |
| InChI key | ROZOUYVVWUTPNG-WDSKDSINSA-N |
安全信息
| 储存分类代码 | 10 - Combustible liquids |
| WGK | WGK 3 |
| 闪点(F) | closed cup |
| 闪点(C) | closed cup |
| 个人防护装备 | Eyeshields, Gloves |
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