产品说明
应用
用于合成手性内酯。
(S)-(-)-1,1′-Binaphthyl-2,2′-diamine may be used in the synthesis of (S)-(+)-N,N′-dimethyl-N,N′-bis{3-[bis-(1-methyl-2-benzimidazolyl methyl)]-amino]-propyl}-1,1′-binaphthyl-2,2′-diamine, an octadentate ligand that can form dinuclear and trinuclear copper(II) complexes. It may also be used in the synthesis of (Sa)-N-[2´-amino-(1,1´-binaphthyl)-2-yl]-4-methylbenzenesulfonamide.
包装
1 g in glass bottle
基本信息
线性分子式 | H2NC10H6C10H6NH2 |
分子量 | 284.35 |
Beilstein | 2419071 |
MDL编号 | MFCD00145204 |
PubChem化学物质编号 | 24863896 |
NACRES | NA.22 |
产品性质
质量水平 | 200 |
测定 | 99% |
旋光性 | [α]20/D −157°, c = 1 in pyridine |
光学纯度 | ee: 99% (HPLC) |
mp | 242-244 ℃ (lit.) |
SMILES string | Nc1ccc2ccccc2c1-c3c(N)ccc4ccccc34 |
InChI | 1S/C20H16N2/c21-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)22/h1-12H,21-22H2 |
InChI key | DDAPSNKEOHDLKB-UHFFFAOYSA-N |
安全信息
象形图 | |
警示用语: | Warning |
危险声明 | H315 - H319 - H335 |
预防措施声明 | P302 + P352 - P305 + P351 + P338 |
危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
靶器官 | Respiratory system |
储存分类代码 | 11 - Combustible Solids |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |
个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
Sigma-Aldrich