产品说明
应用
(+)-3-(Trifluoroacetyl)camphor reacts with suitable chiral ketone precursors to generate chiral dioxiranes in situ, which can catalyse the direct asymmetric epoxidation of unfunctionalized olefins.
包装
1 g in glass bottle
基本信息
| 经验(实验)分子式 | C12H15F3O2 |
| 分子量 | 248.24 |
| Beilstein | 6779716 |
| EC 号 | 257-429-3 |
| MDL编号 | MFCD00003746 |
| PubChem化学物质编号 | 24851361 |
| NACRES | NA.22 |
产品性质
| 测定 | 98% |
| 形式 | liquid |
| 旋光性 | [α]19/D +148°, c = 2.3 in methylene chloride |
| 折射率 | n |
| bp | 100-101 ℃/16 mmHg (lit.) |
| 密度 | 1.172 g/mL at 25 ℃ (lit.) |
| SMILES string | CC1(C)C2CC[C@@]1(C)C(=O)C2C(=O)C(F)(F)F |
| InChI | 1S/C12H15F3O2/c1-10(2)6-4-5-11(10,3)8(16)7(6)9(17)12(13,14)15/h6-7H,4-5H2,1-3H3/t6-,7?,11+/m1/s1 |
| InChI key | ISLOIHOAZDSEAJ-XGLFCGLISA-N |
安全信息
| 象形图 |  |
| 警示用语： | Warning |
| 危险声明 | H315 - H319 - H335 |
| 预防措施声明 | P302 + P352 - P305 + P351 + P338 |
| 危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
| 靶器官 | Respiratory system |
| 储存分类代码 | 10 - Combustible liquids |
| WGK | WGK 3 |
| 闪点(F) | 179.6 °F - closed cup |
| 闪点(C) | 82 ℃ - closed cup |
| 个人防护装备 | Eyeshields, Gloves, type ABEK (EN14387) respirator filter |
Sigma-Aldrich
m.cnreagent.com
