产品说明
应用
Employed in the construction of the key tetrahydropyran subunit in a recent synthesis of the marine natural product (–)-dactylodide.
(tert-Butyldimethylsilyloxy)acetaldehyde is a versatile reagent commonly used in synthetic glycobiology. It can act both as an aldol donor and an aldol acceptor in the stereocontrolled production of erythrose. It is used as an important reagent in the total synthesis of (+)-ambruticin, (−)-laulimalide, (−)-salinosporamide A, and (+)-leucascandrolide A.
包装
1, 5 g in glass bottle
基本信息
| 线性分子式 | (CH3)3CSi(CH3)2OCH2CHO |
| 分子量 | 174.31 |
| MDL编号 | MFCD01321229 |
| PubChem化学物质编号 | 24868481 |
| NACRES | NA.22 |
产品性质
| 测定 | 90% |
| 折射率 | n |
| bp | 165-167 ℃ (lit.) |
| 密度 | 0.915 g/mL at 25 ℃ (lit.) |
| 储存温度 | 2-8℃ |
| SMILES string | CC(C)(C)[Si](C)(C)OCC=O |
| InChI | 1S/C8H18O2Si/c1-8(2,3)11(4,5)10-7-6-9/h6H,7H2,1-5H3 |
| InChI key | MEBFFOKESLAUSJ-UHFFFAOYSA-N |
安全信息
| 象形图 |   |
| 警示用语： | Warning |
| 危险声明 | H226 - H315 - H319 - H335 |
| 预防措施声明 | P210 - P302 + P352 - P305 + P351 + P338 |
| 危险分类 | Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3 |
| 靶器官 | Respiratory system |
| 储存分类代码 | 3 - Flammable liquids |
| WGK | WGK 3 |
| 闪点(F) | 140.0 °F - closed cup |
| 闪点(C) | 60 ℃ - closed cup |
| 个人防护装备 | Eyeshields, Gloves, type ABEK (EN14387) respirator filter |
Sigma-Aldrich
m.cnreagent.com
