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(Tributylphosphoranylidene)acetonitrile

品牌
Sigma-Aldrich
CAS
157141-27-0
货号
761060
包装型号
规格纯度
97%
参考价格
2018.41 *本价格含增值税费
促销
服务
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  • 包邮
  • 增值税票
数量
-+
产品名称:
157141-27-0
(Tributylphosphoranylidene)acetonitrile
(Cyanomethylene)tributylphosphorane
产品介绍:

产品说明

一般描述

(Tributylphosphoranylidene)acetonitrile or cyanomethylenetrimethylphosphorane (Bu3P=CHCN) is a Wittig reagent employed in the transformation of the carbonyl compounds, including aldehydes, esters, and lactones into the corresponding unsaturated nitriles.

应用

(Tributylphosphoranylidene)acetonitrile can be utilized as a reagent in the:

  • Stereoselective synthesis of skytanthine and other O- and N-containing heterocycles by Mitsunobu intramolecular cycloalkylation.
  • Wittig olefination of esters, lactones, N-Boc lactam, and cyclic imide to corresponding Wittig products.

包装

1 g in glass bottle
500 mg in glass bottle

基本信息

经验(实验)分子式C14H28NP
分子量241.35
NACRESNA.22

产品性质

质量水平100
测定97%
形式liquid
折射率n20/D 1.500 (lit.)
密度0.921 g/mL at 25 ℃
储存温度2-8℃

安全信息

储存分类代码12 - Non Combustible Liquids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable

Sigma-Aldrich

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