钯，(醋酸合-ΚO) [2′-[双(1,1-二甲基乙基)膦-ΚP][1,1′-联苯]-2-基 ΚC]

产品名称：

577971-19-8
2-(2′-Di-tert-butylphosphine)biphenylpalladium(II) acetate
Palladium, (acetato-ΚO) [2′-[bis (1,1 dimethylethyl) phosphino-ΚP] [1,1′-biphenyl]-2-yl ΚC]
2-(2′-二叔丁基膦)二苯基钯(II)醋酸盐
钯，(醋酸合-ΚO) [2′-[双(1,1-二甲基乙基)膦-ΚP][1,1′-联苯]-2-基 ΚC]

产品介绍：

产品说明

一般描述

2-(2′-Di-tert-butylphosphine)biphenylpalladium(II) acetate is a novel, air- and moisture-and thermally stable catalyst.

应用

It can be used as a pre-catalyst for the amination of aryl chlorides. It can also be used to prepare N-methyl-6-heterocyclic-1-oxoisoindoline derivatives via Buchwald-Hartwig amination reaction of N-methyl-6- bromoisoindoline-1-one with different amines under microwave condition.
Precatalyst for Buchwald-Hartwig amination reaction.

包装

1 g in glass bottle
250 mg in glass bottle

基本信息

经验(实验)分子式	C₂₂H₂₉O₂PPd
分子量	462.86
MDL编号	MFCD04117716
PubChem化学物质编号	24884102
NACRES	NA.22

产品性质

质量水平	100
测定	97%
reaction suitability	core: palladium reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: catalyst
mp	130-140 ℃ (dec.) (lit.)
SMILES string	CC(=O)[Pd]1c2ccccc2-c3ccccc3[PH]1(C(C)(C)C)C(C)(C)C
InChI	1S/C20H26P.C2H4O2.Pd/c1-19(2,3)21(20(4,5)6)18-15-11-10-14-17(18)16-12-8-7-9-13-16;1-2(3)4;/h7-12,14-15H,1-6H3;1H3,(H,3,4);/q;;+1/p-1
InChI key	IEYDYAASBZOBOC-UHFFFAOYSA-M

安全信息

储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Gloves, type N95 (US)

2-(2′-Di-tert-butylphosphine)biphenylpalladium(II) acetate

Palladium, (acetato-ΚO) [2′-[bis (1,1 dimethylethyl) phosphino-ΚP] [1,1′-biphenyl]-2-yl ΚC]