(3aR,3′aR,8aS,8′aS)-2,2′-(2,6-吡啶二基)双[3a,8a-二氢-8H-茚并[1,2-d]噁唑

产品名称：

357209-32-6
2,6-Bis[(3aR,8aS)-(+)-8H-indeno[1,2-d]oxazolin-2-yl)pyridine
(3aR,8aS)-in-pybox
(3aR,3′aR,8aS,8′aS)-2,2′-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole
2,6-双[(3aR,8aS)-(+)-8H-茚并[1,2-d]噁唑啉-2-基)吡啶
(3aR,3′aR,8aS,8′aS)-2,2′-(2,6-吡啶二基)双[3a,8a-二氢-8H-茚并[1,2-d]噁唑

产品介绍：

产品说明

应用

Catalytic ligand used for:

[3+2] cycloaddition of N-tosyl aziridines with electron-rich alkenes via selective carbon-carbon bond cleavage
Enantioselective Mukaiyama-aldol reactions
Enantioselective carbonyl-ene reactions
Cu(I)-catalyzed asymmetric alkynylation of imino esters with terminal alkynes
Asymmetric three-component coupling reactions catalyzed by a Cu/pybox complex
Enantioselective Diels-Alder reaction
Ni-catalyzed cross-coupling reactions

包装

1 g in glass bottle
250 mg in glass bottle

基本信息

经验(实验)分子式	C₂₅H₁₉N₃O₂
分子量	393.44
MDL编号	MFCD09265074
PubChem化学物质编号	24885191
NACRES	NA.22

产品性质

测定	≥94%
旋光性	[α]20/D +386°, c = 1 in methylene chloride(lit.)
mp	284 ℃ (dec.)
SMILES string	C1[C@@H]2OC(=N[C@@H]2c3ccccc13)c4cccc(n4)C5=N[C@H]6[C@H](Cc7ccccc67)O5
InChI	1S/C25H19N3O2/c1-3-8-16-14(6-1)12-20-22(16)27-24(29-20)18-10-5-11-19(26-18)25-28-23-17-9-4-2-7-15(17)13-21(23)30-25/h1-11,20-23H,12-13H2/t20-,21-,22+,23+/m0/s1
InChI key	BZSJUFJXCHHRHW-MYDTUXCISA-N

安全信息

危险声明	H413
危险分类	Aquatic Chronic 4
储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable