产品说明
应用
用于获得混合金属簇。
Ligand for metal-catalyzed allylic alkylation; decarboxylation of allylic esters; 1,3-diene synthesis; cycloaddition reactions; carbonylation reactions.
包装
10, 50 g in glass bottle
基本信息
线性分子式 | (C6H5)2PCH2CH2P(C6H5)2 |
分子量 | 398.42 |
Beilstein | 761261 |
EC 号 | 216-769-2 |
MDL编号 | MFCD00003047 |
PubChem化学物质编号 | 24846735 |
产品性质
质量水平 | 200 |
测定 | 97% |
reaction suitability | reagent type: ligand reaction type: C-C Bond Formation reagent type: ligand reaction type: Carbonylations reagent type: ligand reaction type: Cycloadditions reagent type: ligand reaction type: Decarboxylations reagent type: ligand reaction type: Diels-Alder Reaction reagent type: ligand reaction type: Heck Reaction reagent type: ligand reaction type: Negishi Coupling reagent type: ligand reaction type: Suzuki-Miyaura Coupling |
mp | 137-142 ℃ (lit.) |
官能团 | phosphine |
SMILES string | C(CP(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4 |
InChI | 1S/C26H24P2/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26/h1-20H,21-22H2 |
InChI key | QFMZQPDHXULLKC-UHFFFAOYSA-N |
安全信息
象形图 | |
警示用语: | Warning |
危险声明 | H335 |
预防措施声明 | P261 - P271 - P304 + P340 + P312 - P403 + P233 - P405 - P501 |
危险分类 | STOT SE 3 |
靶器官 | Respiratory system |
储存分类代码 | 11 - Combustible Solids |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |
个人防护装备 | Eyeshields, Gloves, type N95 (US) |
Sigma-Aldrich