产品说明
包装
1 g in glass bottle
250 mg in glass bottle
应用
Hydroazidation Catalyst for Facile Preparation of Organoazides
SALDIPAC ligand used with Co(BF4)2 (cat. no. 399957) in a hydroazidation of unactivated olefins providing a simple synthesis of alkylazides. The azides, in turn, can be used in a copper-catalyzed cycloaddition with acetylenes providing 1,4-disubstitutedtriazoles.
基本信息
经验(实验)分子式 | C29H32KNO3 |
分子量 | 481.67 |
PubChem化学物质编号 | 24884856 |
NACRES | NA.22 |
产品性质
质量水平 | 100 |
测定 | 95% |
reaction suitability | reagent type: ligand |
mp | 122.2-131.9 ℃ |
SMILES string | CC(C)(C)c1cc(\C=N\C(C(=O)O[K])(c2ccccc2)c3ccccc3)c(O)c(c1)C(C)(C)C |
InChI | 1S/C29H33NO3.K/c1-27(2,3)23-17-20(25(31)24(18-23)28(4,5)6)19-30-29(26(32)33,21-13-9-7-10-14-21)22-15-11-8-12-16-22;/h7-19,31H,1-6H3,(H,32,33);/q;+1/p-1/b30-19+; |
InChI key | ZPKNCDGWTMRAKF-QUIZVCAPSA-M |
安全信息
储存分类代码 | 13 - Non Combustible Solids |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |
Sigma-Aldrich