(2<I>R</I>,3<I>S</I>)-(-)-6-氧代-2,3-二苯基-4-吗啉羧酸苄酯

产品名称：

100516-54-9
(2R,3S)-(-)-N-Z-6-oxo-2,3-diphenylmorpholine
Benzyl (2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
(2R,3S)-(-)-N-Z-6-氧-2,3-二苯基吗啉
(2R,3S)-(-)-6-氧代-2,3-二苯基-4-吗啉羧酸苄酯

产品介绍：

产品说明

应用

(2R,3S)-(−)-N-Z-6-oxo-2,3-diphenylmorpholine is a Williams chiral auxiliary, which can be used:

As a template in the preparation of Fmoc-L-cyclopentylglycine, which acts as an angiotensin II antagonist.
In the synthesis of (L)-Fmoc-α-Me-Lys(Boc)-OH, a building block for the synthesis of peptidomimetics.
To introduce chirality in the modified amino acid named N-Fmoc 4-(2′-(di-tert-butylmalonyl))-l-phenylalanine.

包装

1 g in glass bottle
250 mg in glass bottle

基本信息

经验(实验)分子式	C₂₄H₂₁NO₄
分子量	387.43
MDL编号	MFCD00074958
PubChem化学物质编号	24860004
NACRES	NA.22

产品性质

测定	98%
旋光性	[α]25/D −66°, c = 5.5 in methylene chloride
mp	205-207 ℃ (lit.)
储存温度	2-8℃
SMILES string	O=C1CN([C@H]([C@H](O1)c2ccccc2)c3ccccc3)C(=O)OCc4ccccc4
InChI	1S/C24H21NO4/c26-21-16-25(24(27)28-17-18-10-4-1-5-11-18)22(19-12-6-2-7-13-19)23(29-21)20-14-8-3-9-15-20/h1-15,22-23H,16-17H2/t22-,23+/m0/s1
InChI key	HECRUWTZAMPQOS-XZOQPEGZSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves