产品说明
一般描述
(dppf)Ni(o-tolyl)Cl is an air stable reagent. Its crystal structure has been investigated by X-ray studies. (dppf)Ni(o-tolyl)Cl can be prepared from (Ph3P)2Ni(o-tolyl)Cl. It is widely employed as a precatalyst for various C-N bond formation reactions. Efficacy of (dppf)Ni(o-tolyl)Cl as a precatalyst for the amination of 4-n-butylchlorobenzene with morpholine under various optimized reaction conditions has been investigated.
包装
1 g in glass bottle
250 mg in glass bottle
基本信息
| 经验(实验)分子式 | C41H35ClFeNiP2 |
| 分子量 | 739.66 |
| MDL编号 | MFCD28411349 |
| PubChem化学物质编号 | 329768766 |
产品性质
| 测定 | 95% |
| 质量水平 | 100 |
| 形式 | powder |
| reaction suitability | core: nickel reagent type: catalyst |
| mp | 173 ℃ |
| 储存温度 | 2-8℃ |
| SMILES string | CC1=CC=CC=C1[Ni]Cl.[C]2(P(C3=CC=CC=C3)C4=CC=CC=C4)[C][C][C][C]2.[C]5(P(C6=CC=CC=C6)C7=CC=CC=C7)[C][C][C][C]5.[Fe] |
| InChI | 1S/2C17H14P.C7H7.ClH.Fe.Ni/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;1-7-5-3-2-4-6-7;;;/h2*1-14H;2-5H,1H3;1H;;/q;;;;;+1/p-1 |
| InChI key | LGLPATFHWYLMCO-UHFFFAOYSA-M |
安全信息
| 象形图 |   |
| 警示用语： | Danger |
| 危险声明 | H317 - H334 - H341 - H350 - H360 - H372 - H410 |
| 预防措施声明 | P201 - P273 - P280 - P302 + P352 - P308 + P313 |
| 危险分类 | Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 1 Inhalation |
| 储存分类代码 | 6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects |
| WGK | WGK 3 |
| 闪点(F) | Not applicable |
| 闪点(C) | Not applicable |
Sigma-Aldrich
m.cnreagent.com
