产品说明
一般描述
(Isopropenyloxy)trimethylsilane is an enol silyl ether. It participates as nucleophile in Lewis acid-promoted C3-nucleophile substitution of tetracyclic bromide. It is reported to participate in the total synthesis of (±)-powelline. It is reported to participate in dityltin bis(triflate) catalyzed Michael addition reaction of enol silyl ethers.
包装
1, 5 g in glass bottle
基本信息
线性分子式 | CH3C(=CH2)OSi(CH3)3 |
分子量 | 130.26 |
Beilstein | 1849023 |
EC 号 | 217-393-1 |
MDL编号 | MFCD00042845 |
PubChem化学物质编号 | 24863419 |
NACRES | NA.22 |
产品性质
质量水平 | 100 |
测定 | ≥85% |
杂质 | 10-15% hexamethyldisiloxane |
折射率 | n |
密度 | 0.78 g/mL at 25 ℃ (lit.) |
储存温度 | −20℃ |
SMILES string | CC(=C)O[Si](C)(C)C |
InChI | 1S/C6H14OSi/c1-6(2)7-8(3,4)5/h1H2,2-5H3 |
InChI key | UAIFZYSPVVBOPN-UHFFFAOYSA-N |
安全信息
象形图 | |
警示用语: | Danger |
危险声明 | H225 - H315 - H319 - H335 |
预防措施声明 | P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338 |
危险分类 | Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3 |
靶器官 | Respiratory system |
储存分类代码 | 3 - Flammable liquids |
WGK | WGK 3 |
闪点(F) | 19.4 °F - closed cup |
闪点(C) | -7 ℃ - closed cup |
个人防护装备 | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter |
Sigma-Aldrich