产品说明
一般描述
(R)-(+)-Methyl p-tolyl sulfoxide may be used to prepare (R)-(+)-methyl 3,5-dimethoxy-6-[8-oxo-9-(p-tolylsulfinyl) nonyl] benzoate, an intermediate for (R)-lasiodiplodin synthesis. Its anions undergo addition reaction with nitrones to form optically active a-substituted N-hydroxylamines. (R)-(+)-Methyl p-tolyl sulfoxide also reacts with O-mesitylsulfonylhydroxylamine (MSH) to form (-)-(R)-S-methyl-S-p-tolylsulfoximine.
包装
1 g in glass bottle
基本信息
线性分子式 | CH3C6H4S(O)CH3 |
分子量 | 154.23 |
Beilstein | 2040677 |
MDL编号 | MFCD00151502 |
PubChem化学物质编号 | 24861180 |
NACRES | NA.22 |
产品性质
测定 | 99% |
旋光性 | [α]20/D +145°, c = 2 in acetone |
光学纯度 | ee: 99% (HPLC) |
mp | 73-75 ℃ (lit.) |
SMILES string | Cc1ccc(cc1)S(C)=O |
InChI | 1S/C8H10OS/c1-7-3-5-8(6-4-7)10(2)9/h3-6H,1-2H3/t10-/m1/s1 |
InChI key | FEVALTJSQBFLEU-SNVBAGLBSA-N |
安全信息
储存分类代码 | 13 - Non Combustible Solids |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |
个人防护装备 | Eyeshields, Gloves, type N95 (US) |
Sigma-Aldrich