乙酰基硫甲基-硼烷二苯基膦复合物

产品名称：

446822-71-5
Acetylthiomethyl-diphenylphosphine borane complex
乙酰基硫甲基-硼烷二苯基膦复合物

产品介绍：

产品说明

应用

Traceless Staudinger ligation reagent with borane protecting group.
The borane group stabilizes the phosphine against oxidation and can be easily removed with mild basic or acidic conditions to yield the active phosphine.
After reaction with an azide, the phosphine is eliminated in the presence of water to yield a native amide bond.
Used in the synthesis of cyclic peptides.

包装

1 g in glass bottle
250 mg in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.

法律信息

授权后方可销售，仅供研发使用。美国专利 6,974,884 和相关专利申请

基本信息

产品性质

测定	≥98.0%
reaction suitability	reaction type: click chemistry reagent type: ligand reaction type: Staudinger Reaction
mp	52-55 ℃
储存温度	2-8℃
SMILES string	B.CC(=O)SCP(c1ccccc1)c2ccccc2
InChI	1S/C15H15OPS.BH3/c1-13(16)18-12-17(14-8-4-2-5-9-14)15-10-6-3-7-11-15;/h2-11H,12H2,1H3;1H3
InChI key	MXPNVFCCEGQGEN-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves