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位置:首页 > 品牌 > Sigma-Aldrich > 2,2′-Methylenebis[4,4,5,5-tetramethyl-1,3,2-dioxaborolane]

Bis[(pinacolato)boryl]methane

品牌
Sigma-Aldrich
CAS
78782-17-9
货号
794287
包装型号
规格纯度
参考价格
365.39 *本价格含增值税费
促销
服务
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数量
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产品名称:
78782-17-9
Bis[(pinacolato)boryl]methane
2,2′-Methylenebis[4,4,5,5-tetramethyl-1,3,2-dioxaborolane]
Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methane
产品介绍:

产品说明

一般描述

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
Bis[(pinacolato)boryl]methane is an aryl boronate ester.

应用

Bis-boronate has been reported by Morken and coworkers to be a key building block in the synthesis of enantioenriched secondary boronate esters, which undergo facile Suzuki-Miyaura coupling with minimal erosion of enantiopurity.
Bis[(pinacolato)boryl]methane may be used in the preparation of trans-vinyl boronate esters, via the Boron-Wittig reaction.

包装

1, 5 g in glass bottle

其他说明

A Catalytic Enantiotopic-Group-Selective Suzuki Reaction for the Construction of Chiral Organoboronates

基本信息

经验(实验)分子式C13H26B2O4
分子量267.97
MDL编号MFCD27977747
PubChem化学物质编号329768437

产品性质

环保替代产品特性Catalysis
Learn more about the Principles of Green Chemistry.
质量水平100
mp48 ℃
环保替代产品分类Aligned
储存温度2-8℃
SMILES stringCC(C(C)(C)O1)(C)OB1CB2OC(C)(C)C(C)(C)O2
InChI1S/C13H26B2O4/c1-10(2)11(3,4)17-14(16-10)9-15-18-12(5,6)13(7,8)19-15/h9H2,1-8H3
InChI keyMQYZGGWWHUGYDR-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3

Sigma-Aldrich

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