产品说明
一般描述
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Bis[(pinacolato)boryl]methane is an aryl boronate ester.
应用
Bis-boronate has been reported by Morken and coworkers to be a key building block in the synthesis of enantioenriched secondary boronate esters, which undergo facile Suzuki-Miyaura coupling with minimal erosion of enantiopurity.
Bis[(pinacolato)boryl]methane may be used in the preparation of trans-vinyl boronate esters, via the Boron-Wittig reaction.
包装
1, 5 g in glass bottle
其他说明
A Catalytic Enantiotopic-Group-Selective Suzuki Reaction for the Construction of Chiral Organoboronates
基本信息
经验(实验)分子式 | C13H26B2O4 |
分子量 | 267.97 |
MDL编号 | MFCD27977747 |
PubChem化学物质编号 | 329768437 |
产品性质
环保替代产品特性 | Catalysis Learn more about the Principles of Green Chemistry. |
质量水平 | 100 |
mp | 48 ℃ |
环保替代产品分类 | Aligned |
储存温度 | 2-8℃ |
SMILES string | CC(C(C)(C)O1)(C)OB1CB2OC(C)(C)C(C)(C)O2 |
InChI | 1S/C13H26B2O4/c1-10(2)11(3,4)17-14(16-10)9-15-18-12(5,6)13(7,8)19-15/h9H2,1-8H3 |
InChI key | MQYZGGWWHUGYDR-UHFFFAOYSA-N |
安全信息
象形图 | |
警示用语: | Warning |
危险声明 | H315 - H319 - H335 |
预防措施声明 | P302 + P352 - P305 + P351 + P338 |
危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
靶器官 | Respiratory system |
储存分类代码 | 11 - Combustible Solids |
WGK | WGK 3 |
Sigma-Aldrich