产品名称:
1535-65-5
Difluoromethyl Phenyl Sulfone
[(Difluoromethyl)sulfonyl]benzene
PhSO2CF2H
产品介绍:
产品说明
应用
Reagent Used for
- Reductive silylation and the preparation of trifluoro- and difluoromethylsilanes by reductive coupling of fluoromethyl sulfones, sulfoxides and sulfides with chlorosilanes
- Fluoroalkylation/chloroalkylation of α,β-enones, arynes, acetylenic ketones and other Michael acceptors
- Difluoromethylation of primary alkyl halides via nucleophilic substitution-reductive desulfonylation
Reagent used in Preparation of
- α-difluoromethyl amines via stereoselective (phenylsulfonyl)difluoromethylation of chiral sulfinyl aldimines
- Anti-difluoropropanediols via potassium tert-butoxide-catalyzed difluoromethylenation of aldehydes
- β-difluoromethylated and β-difluoromethylenated alcohols and amines by regioselective nucleophilic difluoromethylation of 1,2-cyclic sulfates and sulfamidates
- Difluoroalkenes from alkyl halides via nucleophilic substitution-elimination
- Difluoromethyl alcohol derivatives from enolizable and non-enolizable carbonyl compounds using nucleophilic phenylsulfonyldifluoromethylation-reductive desulfonylation strategy
- Fluoromethylated vicinal ethylenediamines via fluoromethylation of chiral α-aminobutanesulfinimines with (phenylsulfonyl)fluoromethanes followed by reductive desulfonylation and alcoholysis
基本信息
经验(实验)分子式 | C7H6F2O2S |
分子量 | 192.18 |
Beilstein | 2259218 |
MDL编号 | MFCD01050170 |
PubChem化学物质编号 | 329765583 |
NACRES | NA.22 |
产品性质
质量水平 | 100 |
测定 | ≥97% |
SMILES string | FC(F)S(=O)(=O)c1ccccc1 |
InChI | 1S/C7H6F2O2S/c8-7(9)12(10,11)6-4-2-1-3-5-6/h1-5,7H |
InChI key | LRHDNAVPELLXDL-UHFFFAOYSA-N |
安全信息
象形图 | |
警示用语: | Warning |
危险声明 | H315 - H319 |
预防措施声明 | P302 + P352 - P305 + P351 + P338 |
危险分类 | Eye Irrit. 2 - Skin Irrit. 2 |
储存分类代码 | 10 - Combustible liquids |
WGK | WGK 3 |
闪点(F) | 264.0 °F |
闪点(C) | 128.9 ℃ |