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Difluoromethyl Phenyl Sulfone

品牌
Sigma-Aldrich
CAS
1535-65-5
货号
742600
规格纯度
≥97%
参考价格
532.93 *本价格含增值税费
促销
服务
  • 原厂保证
  • 包邮
  • 增值税票
数量
-+
产品名称:
1535-65-5
Difluoromethyl Phenyl Sulfone
[(Difluoromethyl)sulfonyl]benzene
PhSO2CF2H
产品介绍:

产品说明

应用

Reagent Used for

  • Reductive silylation and the preparation of trifluoro- and difluoromethylsilanes by reductive coupling of fluoromethyl sulfones, sulfoxides and sulfides with chlorosilanes
  • Fluoroalkylation/chloroalkylation of α,β-enones, arynes, acetylenic ketones and other Michael acceptors
  • Difluoromethylation of primary alkyl halides via nucleophilic substitution-reductive desulfonylation

Reagent used in Preparation of
  • α-difluoromethyl amines via stereoselective (phenylsulfonyl)difluoromethylation of chiral sulfinyl aldimines
  • Anti-difluoropropanediols via potassium tert-butoxide-catalyzed difluoromethylenation of aldehydes
  • β-difluoromethylated and β-difluoromethylenated alcohols and amines by regioselective nucleophilic difluoromethylation of 1,2-cyclic sulfates and sulfamidates
  • Difluoroalkenes from alkyl halides via nucleophilic substitution-elimination
  • Difluoromethyl alcohol derivatives from enolizable and non-enolizable carbonyl compounds using nucleophilic phenylsulfonyldifluoromethylation-reductive desulfonylation strategy
  • Fluoromethylated vicinal ethylenediamines via fluoromethylation of chiral α-aminobutanesulfinimines with (phenylsulfonyl)fluoromethanes followed by reductive desulfonylation and alcoholysis

基本信息

经验(实验)分子式C7H6F2O2S
分子量192.18
Beilstein2259218
MDL编号MFCD01050170
PubChem化学物质编号329765583
NACRESNA.22

产品性质

质量水平100
测定≥97%
SMILES stringFC(F)S(=O)(=O)c1ccccc1
InChI1S/C7H6F2O2S/c8-7(9)12(10,11)6-4-2-1-3-5-6/h1-5,7H
InChI keyLRHDNAVPELLXDL-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2
储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)264.0 °F
闪点(C)128.9 ℃

Sigma-Aldrich

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