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Trimethyl(propargyl)silane

炔丙基三甲基硅烷

品牌
Sigma-Aldrich
CAS
13361-64-3
货号
376264
规格纯度
contains 500 ppm BHT as stabilizer
参考价格
1504.52 *本价格含增值税费
促销
服务
  • 原厂保证
  • 包邮
  • 增值税票
数量
-+
产品名称:
13361-64-3
Trimethyl(propargyl)silane
3-(Trimethylsilyl)propyne
2-Propynyl-trimethylsilane
炔丙基三甲基硅烷
三甲基炔丙基硅烷
三甲基炔丙硅烷
产品介绍:

产品说明

一般描述

Trimethyl(propargyl)silane (2-Propynyl-trimethylsilane) is a clear colorless liquid and contains 500ppm of butylated hydroxytoluene (BHT) as stabilizer. It undergoes GaCl3-catalyzed dehydrogenation reaction with aldimines to afford 4-methylquinoline.

应用

Trimethyl(propargyl)silane is suitable for use in the synthesis of diverse end-functionalized (ω-carboxyl, ω-hydroxy, ω-methyl-vinyl, ω-trimethylsilane, and ω-glycidyl-ether) via ′′click′′ reaction. It may be used in the synthesis of γ-allenyl-GABA (γ-aminobutyric acid), via Lewis acid mediated reaction with ω-ethoxy lactams.

包装

1 g in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.

基本信息

线性分子式HC≡CCH2Si(CH3)3
分子量112.24
Beilstein2036316
EC 号236-427-6
MDL编号MFCD00042922
PubChem化学物质编号24863432

产品性质

包含500 ppm BHT as stabilizer
≤20% trimethylallenylsilane (in equilibrium)
质量水平200
折射率n20/D 1.413 (lit.)
bp91-93 ℃ (lit.)
密度0.753 g/mL at 25 ℃ (lit.)
储存温度−20℃
SMILES stringC[Si](C)(C)CC#C
InChI1S/C6H12Si/c1-5-6-7(2,3)4/h1H,6H2,2-4H3
InChI keyULYLMHUHFUQKOE-UHFFFAOYSA-N

安全信息

象形图GHS02GHS07
警示用语:Danger
危险声明H225 - H315 - H319 - H335
预防措施声明P210 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码3 - Flammable liquids
WGKWGK 3
闪点(F)23.0 °F - closed cup
闪点(C)-5 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Sigma-Aldrich

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