产品说明
应用
Grubbs Catalyst® M204 can be used as a catalyst for ring-closing metathesis (RCM), cross-metathesis, and ring-opening metathesis polymerization (ROMP). It is also used to synthesize trisubstituted olefins with excellent functional group tolerance and selectivity via cross-metathesis and ring closing metathesis reactions.
It can also be used as a catalyst:
To synthesize coumarins from phenolic compounds via RCM.
To cleave secondary (E)-allyl vic-diols to aldehydes.
ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.
其他说明
569755 Hoveyda-Grubbs Catalyst 2nd Generation
Grubbs Catalyst Technology for Olefin Metathesis by Aldrich
High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads
Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation
ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand
法律信息
Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG
基本信息
| 经验(实验)分子式 | C46H65Cl2N2PRu |
| 分子量 | 848.97 |
产品性质
| 质量水平 | 100 |
| 测定 | ~4 wt.% loading of catalyst |
| 形式 | solid |
| reaction suitability | reagent type: catalyst core: ruthenium reaction type: Ring-Opening Polymerization |
| 储存温度 | 2-8℃ |
| SMILES string | CC1=CC(C)=CC(C)=C1N(CCN2C3=C(C=C(C=C3C)C)C)[C-2]2=[Ru+6](P(C4CCCCC4)(C5CCCCC5)C6CCCCC6)([Cl-])([Cl-])=[C-2]C7=CC=CC=C7 |
安全信息
| 象形图 |   |
| 警示用语： | Danger |
| 危险声明 | H228 - H350i |
| 预防措施声明 | P201 - P202 - P210 - P240 - P241 - P308 + P313 |
| 危险分类 | Carc. 1B Inhalation - Flam. Sol. 2 |
| 储存分类代码 | 4.1B - Flammable solid hazardous materials |
| WGK | WGK 3 |
| 闪点(F) | Not applicable |
| 闪点(C) | Not applicable |
Sigma-Aldrich
m.cnreagent.com
