产品说明
一般描述
Palladium(II) acetate is a homogenous oxidation catalyst. It participates in the activation of alkenic and aromatic compounds towards oxidative inter- and intramolecular nucleophilic reactions. Crystals of palladium(II) acetate have a trimeric structure, having symmetry D3h. Each of the palladium atoms in the crystals are joined to the other two by double acetate bridges. Microencapsulation of palladium(II) acetate in polyurea affords polyurea-encapsulated palladium(II) acetate. It is a versatile heterogeneous catalyst for various phosphine-free cross-coupling reactions. It participates as catalyst in the Heck coupling reaction of pthalides with different alkenes.
应用
Application Guide for Palladium Catalyzed Cross-Coupling Reactions
Catalyst for an intramolecular coupling of aryl bromides with alcohols giving 1,3-oxazepines. Preparation of cyclic ureas via palladium-catalyzed intramolecular cyclization.
ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.
其他说明
High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads
Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation
ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand
基本信息
| 线性分子式 | Pd(OCOCH3)2 |
| MDL编号 | MFCD00012453 |
产品性质
| 测定 | ~4 wt.% loading of catalyst |
| 质量水平 | 100 |
| 形式 | solid |
| reaction suitability | core: palladium reaction type: Buchwald-Hartwig Cross Coupling Reaction core: palladium reaction type: Heck Reaction core: palladium reaction type: Hiyama Coupling core: palladium reaction type: Negishi Coupling core: palladium reaction type: Sonogashira Coupling core: palladium reaction type: Stille Coupling core: palladium reaction type: Suzuki-Miyaura Coupling reagent type: catalyst |
安全信息
| 象形图 |    |
| 警示用语： | Danger |
| 危险声明 | H317 - H318 - H410 |
| 预防措施声明 | P261 - P272 - P273 - P280 - P302 + P352 - P305 + P351 + P338 |
| 危险分类 | Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Sens. 1A |
| 储存分类代码 | 11 - Combustible Solids |
| WGK | WGK 2 |
| 闪点(F) | Not applicable |
| 闪点(C) | Not applicable |
Sigma-Aldrich
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