产品说明
一般描述
Palladium(II) chloride (PdCl2) reacts with unsubstituted or alkyl-substituted cyclic ketones in the CO atmosphere to afford acyclic diesters and acyclic chloro-substituted monoesters. PdCl2 reacts with N,N-dimethylallylamine in methanol to afford di-μ-chloro-bis(2-methoxy-3-N,N-dimethylaminopropyl)dipalladium(II). Palladium dichloride, acetate and acetylacetonate in the [bmim][BF4] or [bmim][PF6] (where[bmim]+ = 1-butyl-3-methylimidazolium cation) ionic liquids have been employed for the hydrodimerization of butadiene to form octa-2,7-dien-1-ol.
This product is part of a group of 5 products: CHEMBEADS. These materials are made by mixing a catalog product catalyst with glass beads.
应用
Palladium(II) chloride (PdCl2) was used in the following studies:
其他说明
High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads
Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation
ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand
基本信息
经验(实验)分子式 | Cl2Pd |
分子量 | 177.33 |
MDL编号 | MFCD00003558 |
产品性质
测定 | ~4 wt.% loading of catalyst |
质量水平 | 100 |
形式 | solid |
SMILES string | Cl[Pd]Cl |
InChI | 1S/2ClH.Pd/h2*1H;/q;;+2/p-2 |
InChI key | PIBWKRNGBLPSSY-UHFFFAOYSA-L |
安全信息
象形图 | |
警示用语: | Danger |
危险声明 | H290 - H317 - H318 - H350i - H410 |
预防措施声明 | P201 - P273 - P280 - P302 + P352 - P305 + P351 + P338 - P308 + P313 |
危险分类 | Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Eye Dam. 1 - Met. Corr. 1 - Skin Sens. 1 |
储存分类代码 | 6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects |
WGK | WGK 3 |
Sigma-Aldrich