产品说明
一般描述
4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl undergoes one-electron oxidation and reduction reactions. Reaction products were analyzed by 1H, 13C and 15N NMR spectral data.
应用
4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl radical may be employed in the catalytic system used for the regioselective oxidation of curdlan. It may be employed as model nitroxyl radical to study its reaction with thiophosgene. Reaction afforded 2,2,6,6-tetramethylpiperidine and 2,2,6,6-tetramethyl-1-hydroxypiperidine as major products.
其他说明
将醇轻度氧化成羰基的新型氧化剂
基本信息
| 经验(实验)分子式 | C11H21N2O2 |
| 分子量 | 213.30 |
| Beilstein | 3546225 |
| EC 号 | 423-840-3 |
| MDL编号 | MFCD00043593 |
| PubChem化学物质编号 | 329747053 |
| NACRES | NA.22 |
产品性质
| 质量水平 | 200 |
| 等级 | purum |
| 测定 | ≥98.0% (HPLC) |
| 环保替代产品得分 | old score: 9 new score: 8 Find out more about DOZN™ Scoring |
| 环保替代产品特性 | Waste Prevention Safer Solvents and Auxiliaries Inherently Safer Chemistry for Accident Prevention Learn more about the Principles of Green Chemistry. |
| mp | 143-145 ℃ (lit.) 143-146 ℃ |
| 环保替代产品分类 | Re-engineered |
| 储存温度 | 2-8℃ |
| SMILES string | CC(=O)NC1CC(C)(C)N([O])C(C)(C)C1 |
| InChI | 1S/C11H21N2O2/c1-8(14)12-9-6-10(2,3)13(15)11(4,5)7-9/h9H,6-7H2,1-5H3,(H,12,14) |
| InChI key | UXBLSWOMIHTQPH-UHFFFAOYSA-N |
安全信息
| 象形图 |  |
| 警示用语： | Warning |
| 危险声明 | H302 |
| 预防措施声明 | P264 - P270 - P301 + P312 + P330 - P501 |
| 危险分类 | Acute Tox. 4 Oral |
| 储存分类代码 | 13 - Non Combustible Solids |
| WGK | WGK 1 |
| 闪点(F) | Not applicable |
| 闪点(C) | Not applicable |
| 个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
Sigma-Aldrich
m.cnreagent.com
