产品说明
一般描述
(Chloromethyl)cyclopropane on reaction with isolable dialkylsilylene affords 5-silaspiro[4.4]nonane derivative.
应用
(Chloromethyl)cyclopropane was used in the synthesis of (lithiomethyl)cyclopropane and homoallyllithium via 4,4′-di-tert-butylbiphenyl or naphthalene-catalysed lithiation reaction.
包装
10, 50 g in ampule
基本信息
线性分子式 | C3H5CH2Cl |
分子量 | 90.55 |
EC 号 | 227-632-1 |
MDL编号 | MFCD00001307 |
PubChem化学物质编号 | 24851125 |
NACRES | NA.22 |
产品性质
质量水平 | 100 |
测定 | 97% |
形式 | liquid |
折射率 | n |
bp | 87-89 ℃ (lit.) |
密度 | 0.98 g/mL at 25 ℃ (lit.) |
SMILES string | ClCC1CC1 |
InChI | 1S/C4H7Cl/c5-3-4-1-2-4/h4H,1-3H2 |
InChI key | ZVTQWXCKQTUVPY-UHFFFAOYSA-N |
安全信息
象形图 | |
警示用语: | Danger |
危险声明 | H225 - H315 - H319 - H335 |
预防措施声明 | P210 - P302 + P352 - P305 + P351 + P338 |
危险分类 | Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3 |
靶器官 | Respiratory system |
储存分类代码 | 3 - Flammable liquids |
WGK | WGK 3 |
闪点(F) | 28.4 °F - closed cup |
闪点(C) | -2 ℃ - closed cup |
个人防护装备 | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter |
Sigma-Aldrich