三氯氧代 [（二甲基硫醚）三苯基膦氧化物] 铼 (V)

产品名称：

108695-90-5
Oxotrichloro[(dimethylsulfide)triphenylphosphine oxide]rhenium(V)
Trichlorooxo[thiobis[methane]](triphenylphosphine oxide-κO)rhenium
三氯氧代 [（二甲基硫醚）三苯基膦氧化物] 铼 (V)

产品介绍：

产品说明

应用

Catalyst for:

Enantioselective reduction of ketones and imines
Meyer-Schuster rearrangement of propargylic alcohols to α, β-unsaturated carbonyl compounds
Synthesis of 2-deoxy-α glycosides
Sulfurization of phosphorous(III) compounds with thiiranes

Reactant for synthesis of mono and dinuclear compounds
Reagent for rhenium-cyclized somatostatine derivative series synthesis

包装

1 g in glass bottle
250 mg in glass bottle

基本信息

经验(实验)分子式	C₂₀H₂₁Cl₃O₂PReS
分子量	648.98
MDL编号	MFCD08276862
PubChem化学物质编号	24884712
NACRES	NA.22

产品性质

质量水平	100
测定	97%
形式	powder
reaction suitability	core: rhenium reagent type: catalyst
SMILES string	CSC.Cl[Re](Cl)(Cl)=O.O=P(c1ccccc1)(c2ccccc2)c3ccccc3
InChI	1S/C18H15OP.C2H6S.3ClH.O.Re/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-2;;;;;/h1-15H;1-2H3;3*1H;;/q;;;;;;+3/p-3
InChI key	GIBDGLAUIKUJJX-UHFFFAOYSA-K

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves