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(1R)-(-)-Camphorquinone

2,3-莰烷二酮

品牌
Sigma-Aldrich
CAS
10334-26-6
货号
276286
包装型号
规格纯度
99%
参考价格
2028.16 *本价格含增值税费
促销
服务
  • 原厂保证
  • 包邮
  • 增值税票
数量
-+
产品名称:
10334-26-6
(1R)-(-)-Camphorquinone
(1R)-(-)-2,3-Bornanedione
2,3-Bornanedione
(1R)-(-)-樟脑醌
2,3-莰烷二酮
(1R)-(-)-2,3-莰烷二酮
产品介绍:

产品说明

应用

(1R)-(−)-Camphorquinone can be used as a chiral starting material for the preparation of:

  • α-Hydroxycamphors by selective reduction of keto groups using various vegetables.
  • Camphor-1,2-diamine platinum(II) complexes for DNA interaction studies.
  • Camphoric anhydride by unsensitized photo-oxidation in the presence of oxygen and polar solvents.
  • Camphorquinone-based chiral homoallylic amine, which is reacted with aldehydes to produce homoallylic primary amines via imine formation followed by 2-azonia-Cope rearrangement.

包装

5 g in glass bottle

基本信息

经验(实验)分子式C10H14O2
分子量166.22
Beilstein2327696
MDL编号MFCD00082863
PubChem化学物质编号24856697
NACRESNA.22

产品性质

质量水平100
测定99%
旋光性[α]20/D −101°, c = 2 in toluene
mp200-203 ℃ (lit.)
SMILES stringCC1(C)[C@@H]2CC[C@@]1(C)C(=O)C2=O
InChI1S/C10H14O2/c1-9(2)6-4-5-10(9,3)8(12)7(6)11/h6H,4-5H2,1-3H3/t6-,10+/m1/s1
InChI keyVNQXSTWCDUXYEZ-LDWIPMOCSA-N

安全信息

象形图GHS07GHS08
警示用语:Danger
危险声明H302 - H334
预防措施声明P301 + P312 + P330
危险分类Acute Tox. 4 Oral - Resp. Sens. 1
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Sigma-Aldrich

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