产品说明
一般描述
(Triethylsilyl)acetylene, a bulky trialkylsilyl-protected alkyne, undergoes Cadiot-Chodkiewicz cross-coupling reaction with various bromoalkynes to yield synthetically useful unsymmetrical diynes. Rhodium-catalyzed dimerization of (triethylsilyl)acetylene has been reported.
应用
(Triethylsilyl)acetylene may be used in the synthesis of triethylsilylethynyl anthradithiophenes, such as :
包装
5 g in glass bottle
基本信息
线性分子式 | (C2H5)3SiC≡CH |
分子量 | 140.30 |
Beilstein | 1743814 |
MDL编号 | MFCD00075373 |
PubChem化学物质编号 | 24861453 |
NACRES | NA.22 |
产品性质
质量水平 | 100 |
测定 | 97% |
折射率 | n |
密度 | 0.783 g/mL at 25 ℃ (lit.) |
SMILES string | CC[Si](CC)(CC)C#C |
InChI | 1S/C8H16Si/c1-5-9(6-2,7-3)8-4/h1H,6-8H2,2-4H3 |
InChI key | FWSPXZXVNVQHIF-UHFFFAOYSA-N |
安全信息
象形图 | |
警示用语: | Danger |
危险声明 | H225 |
预防措施声明 | P210 - P370 + P378 - P403 + P235 |
危险分类 | Flam. Liq. 2 |
储存分类代码 | 3 - Flammable liquids |
WGK | WGK 3 |
闪点(F) | 62.6 °F - closed cup |
闪点(C) | 17 ℃ - closed cup |
个人防护装备 | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter |
Sigma-Aldrich