氯双环戊基膦

产品名称：

130914-24-8
Chlorodicyclopentylphosphine
Dicyclopentylphosphine chloride
Dicyclopentylchlorophosphine
氯双环戊基膦

产品介绍：

产品说明

一般描述

Chlorodicyclopentylphosphine is a phosphine precursor for ligand preparation in Negishi and Suzuki coupling reactions.
http://citeseerx.ist.psu.edu/viewdoc/download?doi=10.1.1.259.5096&rep=rep1&type=pdf

应用

Chlorodicyclopentylphosphine may be used to prepare:

Cp,Cp-MannOP, a chiral diphosphinite ligand by reacting with mannitol.[Cp=cyclopentyl; Mann=mannitol]
(S)-Cp,Cp-oxoProNOP, a bis(dicycloalkylphosphino) amidophosphine-phosphinite ligand by reacting with (S)-5-(hydroxymethyl)-2-pyrrolidinone
L^cPeNiCl, a precursor for preparing L^cPeNiH, which is an efficient catalyst for the reduction of CO₂[cPe=cyclopentyl]

包装

5 g in glass bottle

基本信息

经验(实验)分子式	C₁₀H₁₈ClP
分子量	204.68
MDL编号	MFCD06798131
PubChem化学物质编号	24883629
NACRES	NA.22

产品性质

质量水平	100
测定	97%
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: ligand
密度	1.069 g/mL at 25 ℃ (lit.)
官能团	phosphine
SMILES string	ClP(C1CCCC1)C2CCCC2
InChI	1S/C10H18ClP/c11-12(9-5-1-2-6-9)10-7-3-4-8-10/h9-10H,1-8H2
InChI key	QTYRJBRBODDGCQ-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H314
预防措施声明	P280 - P305 + P351 + P338 - P310
危险分类	Skin Corr. 1B
补充剂危害	EUH014
储存分类代码	8A - Combustible, corrosive hazardous materials
WGK	WGK 3
闪点(F)	230.0 °F - closed cup
闪点(C)	> 110 ℃ - closed cup
个人防护装备	Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter