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Chlorodicyclopentylphosphine

氯双环戊基膦

品牌
Sigma-Aldrich
CAS
130914-24-8
货号
649066
包装型号
规格纯度
97%
参考价格
1756.95 *本价格含增值税费
促销
服务
  • 原厂保证
  • 包邮
  • 增值税票
数量
-+
产品名称:
130914-24-8
Chlorodicyclopentylphosphine
Dicyclopentylphosphine chloride
Dicyclopentylchlorophosphine
氯双环戊基膦
产品介绍:

产品说明

一般描述

Chlorodicyclopentylphosphine is a phosphine precursor for ligand preparation in Negishi and Suzuki coupling reactions.
http://citeseerx.ist.psu.edu/viewdoc/download?doi=10.1.1.259.5096&rep=rep1&type=pdf

应用

Chlorodicyclopentylphosphine may be used to prepare:

  • Cp,Cp-MannOP, a chiral diphosphinite ligand by reacting with mannitol.[Cp=cyclopentyl; Mann=mannitol]
  • (S)-Cp,Cp-oxoProNOP, a bis(dicycloalkylphosphino) amidophosphine-phosphinite ligand by reacting with (S)-5-(hydroxymethyl)-2-pyrrolidinone
  • LcPeNiCl, a precursor for preparing LcPeNiH, which is an efficient catalyst for the reduction of CO2[cPe=cyclopentyl]

包装

5 g in glass bottle

基本信息

经验(实验)分子式C10H18ClP
分子量204.68
MDL编号MFCD06798131
PubChem化学物质编号24883629
NACRESNA.22

产品性质

质量水平100
测定97%
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
密度1.069 g/mL at 25 ℃ (lit.)
官能团phosphine
SMILES stringClP(C1CCCC1)C2CCCC2
InChI1S/C10H18ClP/c11-12(9-5-1-2-6-9)10-7-3-4-8-10/h9-10H,1-8H2
InChI keyQTYRJBRBODDGCQ-UHFFFAOYSA-N

安全信息

象形图GHS05
警示用语:Danger
危险声明H314
预防措施声明P280 - P305 + P351 + P338 - P310
危险分类Skin Corr. 1B
补充剂危害EUH014
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)230.0 °F - closed cup
闪点(C)> 110 ℃ - closed cup
个人防护装备Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Sigma-Aldrich

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