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Tris(triphenylphosphine)ruthenium(II) Dichloride

三(三苯基膦)二氯化钌(II)

品牌
Sigma-Aldrich
CAS
15529-49-4
货号
223662
规格纯度
97%
参考价格
487.6 *本价格含增值税费
促销
服务
  • 原厂保证
  • 包邮
  • 增值税票
数量
-+
产品名称:
15529-49-4
Tris(triphenylphosphine)ruthenium(II) Dichloride
Tris(triphenylphosphine)dichlororuthenium
Dichlorotris(triphenylphosphine)ruthenium(II)
Ruthenium(II)-tris(triphenylphosphine) dichloride
三(三苯基膦)二氯化钌(II)
三(三苯基膦)氯化钌(II)
三苯基膦氯化钌
三(三苯基膦)二氯钌
产品介绍:

产品说明

应用

Tris(triphenylphosphine)ruthenium(II) dichloride or [RuCl2(PPh3)3] can be used as a catalyst to synthesize:

  • Functionalized alcohols by C-C cross-coupling reaction between different alcohols via sp3 C-H bond activation of primary alcohols in the presence of Lewis acid.
  • Furan derivatives from allenyl sulfides via 1,4 migration of the sulfanyl group.
  • 1,3-diphenylpropan-1-one by alkylation of acetophenone with benzyl alcohol via C-C bond formation.
  • Vinyl chloride monomer by hydrochlorination reaction of acetylene.

RuCl2(PPh3)3 can also be used as a catalyst in the cyclization, isomerization, reduction, oxidation, and cross-coupling reactions of a variety of organic products. Hydrogenation of nitro groups, imines, and ketones, as well as selective oxidation of alcohols are also possible in the presence of this catalyst.

包装

1, 5, 25 g in glass bottle

基本信息

线性分子式[(C6H5)3P]3RuCl2
分子量958.83
Beilstein4935939
EC 号239-569-7
MDL编号MFCD00013077
PubChem化学物质编号24853394
NACRESNA.22

产品性质

质量水平100
测定97%
reaction suitabilitycore: ruthenium
reagent type: catalyst
reaction type: C-H Activation
SMILES stringCl[Ru]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
InChI1S/3C18H15P.2ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h3*1-15H;2*1H;/q;;;;;+2/p-2
InChI keyWIWBLJMBLGWSIN-UHFFFAOYSA-L

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves

Sigma-Aldrich

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