2-Di-<I>tert</I>-butylphosphino-2′,4′,6′-triisopropylbiphenyl

产品名称：

564483-19-8
tBuXPhos
t-Bu XPhos
2-Di-tert-butylphosphino-2′,4′,6′-triisopropylbiphenyl
tert-Butyl XPhos
叔-丁基 XPhos

产品介绍：

产品说明

一般描述

tBuXPhos [2-Di-tert-butylphosphino-2′,4′,6′-triisopropylbiphenyl] is an air-stable, electron-rich biaryl phosphine ligand developed by the Buchwald group to enhance the reactivity of palladium catalysis during cross-coupling reactions.

应用

tBuXPhos has been used in the preparation of [tBuXPhosAu(MeCN)]BAr₄F, a gold catalyst for the intermolecular [2+2] cycloaddition of terminal arylalkynes with substituted alkenes to form functionalized cyclobutenes with high regioselectivity.

法律信息

使用涉及的专利号：EP 1097158；JP 5758844；CA 2336691

基本信息

经验(实验)分子式	C₂₉H₄₅P
分子量	424.64
MDL编号	MFCD06411306

产品性质

测定	95%
形式	powder or crystals
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: ligand
mp	148-151 ℃ (lit.) 150 ℃
官能团	phosphine
SMILES string	CC(C)c1cc(C(C)C)c(c(c1)C(C)C)-c2ccccc2P(C(C)(C)C)C(C)(C)C
InChI	1S/C29H45P/c1-19(2)22-17-24(20(3)4)27(25(18-22)21(5)6)23-15-13-14-16-26(23)30(28(7,8)9)29(10,11)12/h13-21H,1-12H3
InChI key	SACNIGZYDTUHKB-UHFFFAOYSA-N

安全信息

储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable

tBuXPhos

2-Di-tert-butylphosphino-2′,4′,6′-triisopropylbiphenyl