(1<I>S</I>)-1-[(1<I>R</I>)-1-[双[3,5-双(三氟甲基)苯基]膦]乙基]-2-[2-(二苯基膦)苯基]二茂铁（符合 CAS 标准）

(R)-1-{(R_P)-2-[2-(二苯基膦)苯基]二茂铁基}乙基双[3,5-双-(三氟甲基)苯基]膦

品牌

Sigma-Aldrich

CAS

387868-06-6

货号

65671

包装型号

规格纯度

≥97%

参考价格

809.1 元 *本价格含增值税费

促销

数量

产品名称：

387868-06-6
(R)-1-{(R_P)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine
(1S)-1-[(1R)-1-[Bis[3,5-bis(trifluoromethyl)phenyl]phosphino]ethyl]-2-[2-(diphenylphosphino)phenyl]ferrocene (acc to CAS)
Walphos SL-W001-1
(R)-1-{(R_P)-2-[2-(二苯基膦)苯基]二茂铁基}乙基双[3,5-双-(三氟甲基)苯基]膦
(1S)-1-[(1R)-1-[双[3,5-双(三氟甲基)苯基]膦]乙基]-2-[2-(二苯基膦)苯基]二茂铁（符合 CAS 标准）

产品介绍：

产品说明

一般描述

The product is an air-stable and non-hygroscopic Solvias chiral phosphine ligand.

应用

Walphos SL-W001-1, in the presence of a ruthenium catalyst may be used as a ligand in the following processes:

Asymmetric hydrogenation of IPCA-D, a cinnamic acid derivative.
Addition of 3,5-difluorophenylketimine to 4-methoxyphenylboronic acid to form the corresponding tertiary substituted cyclic sulfamate derivative with high enantioselctivity.2

包装

1, 5 g in glass bottle
100, 500 mg in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.

其他说明

与 Solvias AG 合作销售

基本信息

经验(实验)分子式	C₄₆H₃₂F₁₂FeP₂
分子量	930.52
MDL编号	MFCD08561122
PubChem化学物质编号	24884219
NACRES	NA.22

产品性质

质量水平	100
测定	≥97%
光学纯度	ee: ≥99%
SMILES string	[Fe].[CH]1[CH][CH][CH][CH]1.C[C@@H]([C]2[CH][CH][CH][C]2c3ccccc3P(c4ccccc4)c5ccccc5)P(c6cc(cc(c6)C(F)(F)F)C(F)(F)F)c7cc(cc(c7)C(F)(F)F)C(F)(F)F
InChI	1S/C41H27F12P2.C5H5.Fe/c1-25(34-16-10-17-35(34)36-15-8-9-18-37(36)55(30-11-4-2-5-12-30)31-13-6-3-7-14-31)54(32-21-26(38(42,43)44)19-27(22-32)39(45,46)47)33-23-28(40(48,49)50)20-29(24-33)41(51,52)53;1-2-4-5-3-1;/h2-25H,1H3;1-5H;/t25-;;/m0../s1
InChI key	LKNKYBWIZNAXBY-WLOLSGMKSA-N

安全信息

储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Gloves, type N95 (US)

(R)-1-{(RP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine

(R)-1-{(RP)-2-[2-(二苯基膦)苯基]二茂铁基}乙基双[3,5-双-(三氟甲基)苯基]膦

(R)-1-{(R_P)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine

(R)-1-{(R_P)-2-[2-(二苯基膦)苯基]二茂铁基}乙基双[3,5-双-(三氟甲基)苯基]膦