(<i>R</i>)-(+)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine)

(R)-(+)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine)

品牌

Sigma-Aldrich

CAS

133545-16-1

货号

29510

包装型号

规格纯度

≥97%, optical purity ee: ≥99%

参考价格

126665 元 *本价格含增值税费

促销

数量

产品名称：

133545-16-1
(R)-(+)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine)
SL-A101-1
(R)-(+)-2,2′-Bis(diphenylphosphino)-6,6′-dimethoxy-1,1′-biphenyl
(R)-(+)-MeO-BIPHEP
(R)-(+)-(6,6′-二甲氧联苯-2,2′-二基)双(二苯基膦)
(R)-(+)-2,2′-双(二苯基膦)-6,6′-二甲氧-1,1′-联苯

产品介绍：

产品说明

一般描述

与 Solvias AG 联合销售
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

应用

Ligand for ruthenium-catalyzed greener amine synthesis by enamine reduction with hydrogen gas.

Asymmetric Synthesis of (S)-3-Amino-4-methoxy-butan-1-ol by Way of Reductive Amination
Atropisomeric diphosphine; the Rh(I) complex is employed for highly enantioselective asymmetric isomerization of allylamines to enamines; the Ru(II) complex hydrogenates ß-keto esters in high enantioselectivity; the Pd(0) complex for cyclization of hydroxy allylic carbonates.
Atropisomeric MeOBIPHEP ligands

Hydrogenation of α- and β-functionalized ketones
Hydrogenation of heteroarenes
C–C coupling reactions

包装

Bottomless glass bottle. Contents are inside inserted fused cone.

基本信息

经验(实验)分子式	C₃₈H₃₂O₂P₂
分子量	582.61
Beilstein	4790083
MDL编号	MFCD03095430
PubChem化学物质编号	24857757
NACRES	NA.22

产品性质

质量水平	100
测定	≥97%
光学纯度	ee: ≥99%
环保替代产品特性	Catalysis Learn more about the Principles of Green Chemistry.
环保替代产品分类	Aligned
SMILES string	COc1cccc(P(c2ccccc2)c3ccccc3)c1-c4c(OC)cccc4P(c5ccccc5)c6ccccc6
InChI	1S/C38H32O2P2/c1-39-33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)38-34(40-2)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32/h3-28H,1-2H3
InChI key	KRJVQCZJJSUHHO-UHFFFAOYSA-N

安全信息

储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Gloves, type N95 (US)