(<I>R</I>,<I>R</I>)-1,2-乙烷二基双[(2-甲氧基苯基)苯基膦]

产品名称：

55739-58-7
(R,R)-DIPAMP
(R,R)-Ethylenebis[(2-methoxyphenyl)phenylphosphine]
(R,R)-1,2-Bis[(2-methoxyphenyl)(phenylphosphino)]ethane
(R,R)-1,2-Ethanediylbis[(2-methoxyphenyl)phenylphosphine]
[(1R,2R)-(-)-Bis[(2-methoxyphenyl)phenylphosphino]ethane]
(R,R)-乙烯二[(2-甲氧基苯基)苯基膦]
(R,R)-1,2-双[(2-甲氧基苯基)(苯基膦基)]乙烷
(R,R)-1,2-乙烷二基双[(2-甲氧基苯基)苯基膦]
[(1R,2R)-(-)-双[(2-甲氧基苯基)苯基膦]乙烷]

产品介绍：

产品说明

应用

(R, R)-DIPAMP can be used:

As a catalyst in the enantioselective [3+2] cycloaddition of γ-substituted allenoates with β-perfluoroalkyl enones and 3-butynoates with electron-deficient olefins to yield substituted cyclopentenes.
To prepare its rhodium metal complexes, which are used as catalysts in asymmetric hydrogenation reactions.

包装

100, 500 mg in amber glass bottle

基本信息

线性分子式	[CH₃OC₆H₄P(C₆H₅)CH₂-]₂
分子量	458.47
MDL编号	MFCD05863546
PubChem化学物质编号	329761951
NACRES	NA.22

产品性质

质量水平	100
测定	95%
旋光性	[α]22/D −81°, c = 1 in chloroform
mp	102-106 ℃ (lit.)
SMILES string	COc1ccccc1P(CCP(c2ccccc2)c3ccccc3OC)c4ccccc4
InChI	1S/C28H28O2P2/c1-29-25-17-9-11-19-27(25)31(23-13-5-3-6-14-23)21-22-32(24-15-7-4-8-16-24)28-20-12-10-18-26(28)30-2/h3-20H,21-22H2,1-2H3/t31-,32-/m1/s1
InChI key	QKZWXPLBVCKXNQ-ROJLCIKYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335 - H413
预防措施声明	P273 - P302 + P352 - P305 + P351 + P338
危险分类	Aquatic Chronic 4 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

(R,R)-DIPAMP

(R,R)-乙烯二[(2-甲氧基苯基)苯基膦]