1,5-环辛二烯双(甲基联苯基磷化氢)铱六氟磷酸盐

产品名称：

38465-86-0
(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate
{Ir(COD)[PCH₃(C₆H₅)₂]₂}PF₆
[Ir(cod)(PPh₂Me)₂]PF₆
[Ir(PMePh₂)₂COD]⁺ PF₆^-
1,5-环辛二烯双(甲基联苯基磷化氢)铱六氟磷酸盐

产品介绍：

产品说明

应用

(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate is an air-stable cationic iridium complex, generally employed in allyl isomerization reactions. Upon bubbling hydrogen into the solution of [Ir(cod)(PPh₂Me)₂]PF₆, preferably in tetrahydrofuran, results in the formation of active catalyst [IrH₂(solv)₂(PPh₂Me)₂]PF₆ which can be used in the isomerization of 3-(silyloxy)-1-propenylboronates to (γ-(silyloxy)allyl)boronic esters; diallyl ethers to allyl (E)-vinyl ethers and 1-alkenylboronates to corresponding 3-alkoxyallylboronates.

包装

50, 500 mg in glass bottle

基本信息

经验(实验)分子式	C₃₄H₃₈F₆IrP₃
分子量	845.79
MDL编号	MFCD00064800
PubChem化学物质编号	24860482
NACRES	NA.22

产品性质

质量水平	100
测定	97%
reaction suitability	core: iridium reagent type: catalyst
mp	224 ℃ (dec.) (lit.)
SMILES string	[Ir+].F[P-](F)(F)(F)(F)F.C1CC=CCCC=C1.CP(c2ccccc2)c3ccccc3.CP(c4ccccc4)c5ccccc5
InChI	1S/2C13H13P.C8H12.F6P.Ir/c21-14(12-8-4-2-5-9-12)13-10-6-3-7-11-13;1-2-4-6-8-7-5-3-1;1-7(2,3,4,5)6;/h22-11H,1H3;1-2,7-8H,3-6H2;;/q;;;-1;+1/b;;2-1-,8-7-;;
InChI key	LXKHQEQLBSJJCO-JXNOXZOESA-N

安全信息

象形图
警示用语：	Warning
危险声明	H302 + H312 + H332 - H315 - H319 - H335
预防措施声明	P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
危险分类	Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves