产品说明
一般描述
Methyl 3-bromobenzoate is an aryl bromide. It undergoes stereoconvergent cross-coupling with potassium trifluoro(1-phenylethyl)borate to form 1,1-diarylethane derivative. The Negishi cross-coupling reaction between methyl 3-bromobenzoate and diarylzinc reagents in the presence of a palladium catalyst has been reported. Methyl-3-bromobenzoate can be converted into the corresponding benzonitrile using dichloro[bis{1-(dicyclohexylphosphanyl)piperidine}]palladium as a C-C cross-coupling catalyst and K4[Fe(CN)6] as a cyanating agent.
包装
5, 25 g in glass bottle
基本信息
| 线性分子式 | BrC6H4CO2CH3 |
| 分子量 | 215.04 |
| EC 号 | 210-569-9 |
| MDL编号 | MFCD00017777 |
| PubChem化学物质编号 | 24873294 |
| NACRES | NA.22 |
产品性质
| 质量水平 | 200 |
| 测定 | 98% |
| bp | 127-128 ℃/15 mmHg (lit.) |
| mp | 31-33 ℃ (lit.) |
| SMILES string | COC(=O)c1cccc(Br)c1 |
| InChI | 1S/C8H7BrO2/c1-11-8(10)6-3-2-4-7(9)5-6/h2-5H,1H3 |
| InChI key | KMFJVYMFCAIRAN-UHFFFAOYSA-N |
安全信息
| 储存分类代码 | 13 - Non Combustible Solids |
| WGK | WGK 3 |
| 闪点(F) | Not applicable |
| 闪点(C) | Not applicable |
| 个人防护装备 | Eyeshields, Gloves, type N95 (US) |
Sigma-Aldrich
m.cnreagent.com
