α-(三甲基硅氧基)苯乙烯

产品名称：

13735-81-4
1-Phenyl-1-trimethylsiloxyethylene
α-(Trimethylsiloxy)styrene
Acetophenone enol trimethylsilyl ether
1-苯基-1-三甲基硅氧乙烯
1-苯基-1-三甲硅氧基乙烯
α-(三甲基硅氧基)苯乙烯

产品介绍：

产品说明

一般描述

1-Phenyl-1-trimethylsiloxyethylene is a styrene type silyl enol ether, reacts with formaldehyde and 2,4-pentanedione to yield the corresponding dihydropyran. It also undergoes Mukaiyama aldol reaction with aldehydes in water in the presence of amphiphilic calix[6]arene derivatives as surfactants.

应用

1-Phenyl-1-trimethylsiloxyethylene has been used in the synthesis of:

β-amino ketones in water via Mannich-type reaction
cis-2,6-disubstituted dihydropyrans via three-component, one-pot cascade reaction

包装

5, 25 g in glass bottle

基本信息

线性分子式	C₆H₅C(=CH₂)OSi(CH₃)₃
分子量	192.33
Beilstein	1306914
EC 号	237-308-1
MDL编号	MFCD00008582
PubChem化学物质编号	24854075
NACRES	NA.22

产品性质

质量水平	100
蒸汽密度	>1 (vs air)
测定	98%
形式	liquid
折射率	n20/D 1.502 (lit.)
bp	88-89 ℃/11 mmHg (lit.)
密度	0.938 g/mL at 25 ℃ (lit.)
储存温度	2-8℃
SMILES string	C[Si](C)(C)OC(=C)c1ccccc1
InChI	1S/C11H16OSi/c1-10(12-13(2,3)4)11-8-6-5-7-9-11/h5-9H,1H2,2-4H3
InChI key	AFFPCIMDERUIST-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	10 - Combustible liquids
WGK	WGK 3
闪点(F)	168.8 °F - closed cup
闪点(C)	76 ℃ - closed cup
个人防护装备	Eyeshields, Gloves, type ABEK (EN14387) respirator filter