产品说明
应用
(S)-(+)-1-(2-Pyrrolidinylmethyl)pyrrolidine can be used as an organocatalyst in the asymmetric synthesis of different optically active organic building blocks via Aldol condensation and Mannich reactions . It is also used as a catalyst to prepare enantioselective Michael adducts by reacting alkylidene malonates with unactivated ketones.
包装
1 g in glass bottle
250 mg in amber glass bottle
基本信息
| 经验(实验)分子式 | C9H18N2 |
| 分子量 | 154.25 |
| MDL编号 | MFCD00013441 |
| PubChem化学物质编号 | 24859441 |
| NACRES | NA.22 |
产品性质
| 质量水平 | 100 |
| 测定 | 96% |
| 旋光性 | [α]19/D +7.0°, c = 2.4 in ethanol |
| 折射率 | n |
| bp | 99-101 ℃/2 mmHg (lit.) |
| 密度 | 0.946 g/mL at 25 ℃ (lit.) |
| SMILES string | C1CCN(C1)C[C@@H]2CCCN2 |
| InChI | 1S/C9H18N2/c1-2-7-11(6-1)8-9-4-3-5-10-9/h9-10H,1-8H2/t9-/m0/s1 |
| InChI key | YLBWRMSQRFEIEB-VIFPVBQESA-N |
安全信息
| 象形图 |  |
| 警示用语： | Warning |
| 危险声明 | H315 - H319 - H335 |
| 预防措施声明 | P302 + P352 - P305 + P351 + P338 |
| 危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
| 靶器官 | Respiratory system |
| 储存分类代码 | 10 - Combustible liquids |
| WGK | WGK 3 |
| 闪点(F) | 190.4 °F - closed cup |
| 闪点(C) | 88 ℃ - closed cup |
| 个人防护装备 | Eyeshields, Gloves, type ABEK (EN14387) respirator filter |
Sigma-Aldrich
m.cnreagent.com
