三甲基硅烷基乙炔锂溶液

产品名称：

54655-07-1
Lithium (trimethylsilyl)acetylide solution
(Trimethylsilyl)ethynyllithium
三甲基硅烷基乙炔锂溶液
三甲基硅基乙炔锂

产品介绍：

产品说明

应用

Reacts with halotriazines to produce conductive, anisotropic carbon-nitrogen materials.
Lithium (trimethylsilyl)acetylide can be used as a reagent:

In the transmetalation and nucleophilic displacement reactions.
To prepare propargylic alcohol derivatives by reacting with aldehydes and ketones.
To synthesize α,βynones by treating with Weinreb amide or with isoxazolidide.
Along with Grignard reagent to convert γ- and δ-thiolactams to thioiminium salts, which are employed as key intermediates to produce disubstituted pyrrolidines.

包装

4×25, 50, 500 mL in Sure/Seal™
The 25 mL Sure/Seal^™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

法律信息

Sure/Seal is a trademark of sigma-aldrich Co. LLC

基本信息

线性分子式	(CH₃)₃SiC≡CLi
分子量	104.15
Beilstein	3587411
MDL编号	MFCD00075059
PubChem化学物质编号	24860321
NACRES	NA.22

产品性质

质量水平	100
浓度	0.5 M in THF
密度	0.88 g/mL at 25 ℃
SMILES string	[Li]C#C[Si](C)(C)C
InChI	1S/C5H9Si.Li/c1-5-6(2,3)4;/h2-4H3;
InChI key	ZVXXEONXFWSCIZ-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H225 - H302 - H314 - H335 - H351
预防措施声明	P210 - P260 - P280 - P305 + P351 + P338 - P370 + P378 - P403 + P235
危险分类	Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
靶器官	Respiratory system
补充剂危害	EUH019
储存分类代码	3 - Flammable liquids
WGK	WGK 3
闪点(F)	-9.4 °F - closed cup
闪点(C)	-23 ℃ - closed cup
个人防护装备	Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter