产品说明
应用
2-Methylallylmagnesium chloride is a general Grignard reagent used in the synthesis of (−)-aplysin, acutumine, dimedol and allyldicyclopentadienyltitanium(III) complexes.
包装
4×25, 100 mL in Sure/Seal™
The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
法律信息
Sure/Seal is a trademark of sigma-aldrich Co. LLC
基本信息
线性分子式 | H2C=C(CH3)CH2MgCl |
分子量 | 114.86 |
MDL编号 | MFCD00674003 |
PubChem化学物质编号 | 24866258 |
NACRES | NA.22 |
产品性质
质量水平 | 100 |
reaction suitability | reaction type: Grignard Reaction |
浓度 | 0.5 M in THF |
bp | 65-67 ℃ |
密度 | 0.915 g/mL at 25 ℃ |
SMILES string | CC(=C)C[Mg]Cl |
InChI | 1S/C4H7.ClH.Mg/c1-4(2)3;;/h1-2H2,3H3;1H;/q;;+1/p-1 |
InChI key | BJVFGWYBOLMUEM-UHFFFAOYSA-M |
安全信息
象形图 | |
警示用语: | Danger |
危险声明 | H225 - H261 - H302 - H314 - H335 - H351 |
预防措施声明 | P210 - P231 + P232 - P280 - P370 + P378 - P402 + P404 - P403 + P235 |
危险分类 | Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 2 |
靶器官 | Respiratory system |
补充剂危害 | EUH014 - EUH019 |
储存分类代码 | 4.3 - Hazardous materials, which set free flammable gases upon contact with water |
WGK | WGK 3 |
闪点(F) | -5.8 °F - closed cup |
闪点(C) | -21 ℃ - closed cup |
个人防护装备 | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter |
Sigma-Aldrich