产品说明
一般描述
tert-Butyldimethylsilyl glycidyl ether [tert-butyl-dimethyl-(oxiran-2-ylmethoxy)silane] can be synthesized from glycidol, via hydrolytic kinetic resolution (HKR) in the presence of R-(salen)Co complex and water.
应用
tert-Butyldimethylsilyl glycidyl ether may be used to synthesize (R/S)-1-benzylamino-3-(tert-butyldimethylsilyloxy)propan-2-ol and (2R/2S)-1-(tert-butyldimethylsilyloxy)-3-{[(4S)-2,2-dimethyl-1,3-dioxolan-4-ylmethyl]amino}propan-2-ol.
包装
10 g in glass bottle
基本信息
经验(实验)分子式 | C9H20O2Si |
分子量 | 188.34 |
MDL编号 | MFCD02683555 |
PubChem化学物质编号 | 24874536 |
产品性质
测定 | 98% |
折射率 | n |
bp | 195-197 ℃ (lit.) |
密度 | 0.901 g/mL at 25 ℃ (lit.) |
SMILES string | CC(C)(C)[Si](C)(C)OCC1CO1 |
InChI | 1S/C9H20O2Si/c1-9(2,3)12(4,5)11-7-8-6-10-8/h8H,6-7H2,1-5H3 |
InChI key | YANSSVVGZPNSKD-UHFFFAOYSA-N |
安全信息
储存分类代码 | 10 - Combustible liquids |
WGK | WGK 3 |
闪点(F) | 158.0 °F - closed cup |
闪点(C) | 70 ℃ - closed cup |
个人防护装备 | Eyeshields, Gloves, multi-purpose combination respirator cartridge (US) |
Sigma-Aldrich