产品说明
一般描述
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 0.5 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention. Click here for more information.
应用
Significantly accelerated the polymerization of phenylacetylene in conjunction with rhodium(I) catalysis.
Strong organic base in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).
2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
包装
4×25, 100, 800 mL in Sure/Seal™
The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
法律信息
Sure/Seal is a trademark of sigma-aldrich Co. LLC
基本信息
| 线性分子式 | [(CH3)3Si]2NLi |
| 分子量 | 167.33 |
| Beilstein | 3567910 |
| MDL编号 | MFCD00008261 |
| PubChem化学物质编号 | 329767733 |
| NACRES | NA.22 |
产品性质
| 形式 | liquid |
| 质量水平 | 100 |
| 环保替代产品特性 | Safer Solvents and Auxiliaries Use of Renewable Feedstocks Inherently Safer Chemistry for Accident Prevention Learn more about the Principles of Green Chemistry. |
| 浓度 | 0.5 M in 2-methyltetrahydrofuran |
| 密度 | 0.857 g/mL at 25 ℃ |
| 环保替代产品分类 | Aligned |
| SMILES string | [Li]N([Si](C)(C)C)[Si](C)(C)C |
| InChI | 1S/C6H18NSi2.Li/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1 |
| InChI key | YNESATAKKCNGOF-UHFFFAOYSA-N |
安全信息
| 象形图 |    |
| 警示用语： | Danger |
| 危险声明 | H225 - H251 - H302 - H314 |
| 预防措施声明 | P210 - P235 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338 |
| 危险分类 | Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Self-heat. 1 - Skin Corr. 1B |
| 补充剂危害 | EUH014 - EUH019 |
| 储存分类代码 | 4.2 - Pyrophoric and self-heating hazardous materials |
| WGK | WGK 2 |
| 闪点(F) | 8.6 °F |
| 闪点(C) | -13 ℃ |
Sigma-Aldrich
m.cnreagent.com
