产品说明
应用
2,2′-Methylenebis[(4S)-4-tert-butyl-2-oxazoline] (BOX ligand) can be used as a C2 symmetric ligand for enantioselective asymmetric catalysis. It easily forms bidentate coordination complexes due to the strong affinity of the oxazoline nitrogen for various metals.
对映选择性催化反应的 C2 对称配体由于噁唑啉氮具有对各种金属的强亲合性,因此可容易地形成双齿配位络合物。
包装
500 mg in glass bottle
基本信息
经验(实验)分子式 | C15H26N2O2 |
分子量 | 266.38 |
Beilstein | 4190673 |
MDL编号 | MFCD00192290 |
PubChem化学物质编号 | 24865343 |
NACRES | NA.22 |
产品性质
测定 | 99% |
旋光性 | [α]20/D −118°, c = 0.5 in chloroform |
mp | 51-53 ℃ (lit.) |
SMILES string | CC(C)(C)[C@H]1COC(CC2=N[C@H](CO2)C(C)(C)C)=N1 |
InChI | 1S/C15H26N2O2/c1-14(2,3)10-8-18-12(16-10)7-13-17-11(9-19-13)15(4,5)6/h10-11H,7-9H2,1-6H3/t10-,11-/m1/s1 |
InChI key | WCCCBUXURHZPQL-GHMZBOCLSA-N |
安全信息
象形图 | |
警示用语: | Warning |
危险声明 | H315 - H319 - H335 |
预防措施声明 | P302 + P352 - P305 + P351 + P338 |
危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
靶器官 | Respiratory system |
储存分类代码 | 11 - Combustible Solids |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |
个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
Sigma-Aldrich