产品说明
一般描述
5-Isopropyl-1,3-cyclohexanedione is a cyclic 1,3-diketone. It can be prepared by condensation of isobutylideneacetone with ethyl malonate. 5-Isopropyl-1,3-cyclohexanedione on methylation with methyl iodide yields 5-isopropyl-2-methyl-1,3-cyclohexanedione. A multistep-synthesis of 5-isopropyl-1,3-cyclohexanedione involving aldol condensation, Dieckmann-type annulation, ester hydrolysis and decarboxylation is reported.
应用
5-Isopropyl-1,3-cyclohexanedione may be used as starting reagent for the synthesis of carvotanacetone analogs. It may be used in the preparation of monocyclic terepenes. It may be used in the synthesis of 2H-pyrans, via reaction with α,β-unsaturated aldehydes.
包装
5 g in poly bottle
基本信息
| 线性分子式 | (CH3)2CHC6H7(=O)2 |
| 分子量 | 154.21 |
| MDL编号 | MFCD00150873 |
| PubChem化学物质编号 | 24861163 |
| NACRES | NA.22 |
产品性质
| 质量水平 | 100 |
| 测定 | 99% (GC) |
| mp | 63-65 ℃ (lit.) |
| 运输 | dry ice |
| SMILES string | [H]O[H].CC(C)C1CC(=O)CC(=O)C1 |
| InChI | 1S/C9H14O2.H2O/c1-6(2)7-3-8(10)5-9(11)4-7;/h6-7H,3-5H2,1-2H3;1H2 |
| InChI key | JYJVWRORYGGPHA-UHFFFAOYSA-N |
安全信息
| 储存分类代码 | 11 - Combustible Solids |
| WGK | WGK 3 |
| 闪点(F) | Not applicable |
| 闪点(C) | Not applicable |
| 个人防护装备 | Eyeshields, Gloves, type N95 (US) |
Sigma-Aldrich
m.cnreagent.com
