双(2,2,2-三氟乙基)(甲氧羰基甲基)膦酸酯

产品名称：

88738-78-7
Methyl P,P-bis(2,2,2-trifluoroethyl)phosphonoacetate
Bis(2,2,2-trifluoroethyl) (Methoxycarbonylmethyl)phosphonate
O,O'-双(2,2,2-三氟乙基)磷乙酸甲酯
双(2,2,2-三氟乙基)(甲氧羰基甲基)膦酸酯

产品介绍：

产品说明

应用

Methyl P,P-bis(2,2,2-trifluoroethyl)phosphonoacetate can be used:

In one of the key synthetic steps for the preparation of trans-hydrindanes and (R)-(+)-umbelactone.
To prepare a cis-olefinic ester derivative by Still–Gennari olefination of an aldehyde derivative using 18-crown ether and potassium bis(trimethylsilyl)amide (KHMDS).
In the synthesis of (−)-(6S,2′S)-epi cryptocaryalactone.

包装

5 g in glass bottle

基本信息

线性分子式	CH₃O₂CCH₂P(O)(OCH₂CF₃)₂
分子量	318.11
Beilstein	3594044
MDL编号	MFCD00009901
PubChem化学物质编号	24856576
NACRES	NA.22

产品性质

测定	95%
形式	liquid
reaction suitability	reaction type: C-C Bond Formation
折射率	n20/D 1.370 (lit.)
密度	1.504 g/mL at 25 ℃ (lit.)
SMILES string	COC(=O)CP(=O)(OCC(F)(F)F)OCC(F)(F)F
InChI	1S/C7H9F6O5P/c1-16-5(14)2-19(15,17-3-6(8,9)10)18-4-7(11,12)13/h2-4H2,1H3
InChI key	PVSJXEDBEXYLML-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	10 - Combustible liquids
WGK	WGK 3
闪点(F)	230.0 °F - closed cup
闪点(C)	110 ℃ - closed cup
个人防护装备	Eyeshields, Gloves, type ABEK (EN14387) respirator filter