(-)-甲基苯基甲醇

产品名称：

1445-91-6
(S)-(-)-1-Phenylethanol
(S)-(-)-sec-Phenylethyl alcohol
(-)-Methyl phenyl carbinol
(S)-(-)-α-Methylbenzyl alcohol
(S)-(-)-1-苯乙醇
(-)-甲基苯基甲醇
(S)-(-)-α-甲基苄醇
(S)-(- 秒 -苯乙醇

产品介绍：

产品说明

一般描述

(S)-(-)-1-Phenylethanol can be prepared from acetophenone via enantioselective bioreduction in the presence of Rhizopus arrhizus as a biocatalyst.

应用

(S)-(-)-1-Phenylethanol can be used as:

A starting material to prepare (1S,3R,4S)-1-methyl-3,4-diphenyl-3,4-dihydro-1H-isochromene-3,4-diol (a cyclic hemiacetal) by reacting with benzil via dilithiation reaction.
A chiral solvent in the symmetric synthesis of substituted spiroundecenetriones via amino acid-catalyzed domino Knoevenagel/Diels-Alder reactions.

基本信息

经验(实验)分子式	C₈H₁₀O
分子量	122.16
Beilstein	2039797
MDL编号	MFCD00064264
PubChem化学物质编号	329748080
NACRES	NA.22

产品性质

质量水平	100
测定	≥98.5% (sum of enantiomers, GC)
形式	liquid
旋光性	[α]/D −45±2°, c = 5% in methanol
光学纯度	enantiomeric ratio: ≥97:3 (GC)
折射率	n20/D 1.527
bp	88-89 ℃/10 mmHg (lit.)
mp	9-11 ℃ (lit.)
密度	1.012 g/mL at 20 ℃ (lit.)
SMILES string	C[C@H](O)c1ccccc1
InChI	1S/C8H10O/c1-7(9)8-5-3-2-4-6-8/h2-7,9H,1H3/t7-/m0/s1
InChI key	WAPNOHKVXSQRPX-ZETCQYMHSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H302 - H315 - H319
预防措施声明	P301 + P312 + P330 - P302 + P352 - P305 + P351 + P338
危险分类	Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
储存分类代码	6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK	WGK 3
闪点(F)	185.0 °F
闪点(C)	85 ℃
个人防护装备	Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter