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2-Benzyloxyphenylmagnesium bromide solution

2-苄氧基苯基溴化镁 溶液

品牌
Sigma-Aldrich
CAS
328000-16-4
货号
673013
包装型号
规格纯度
1.0 M in THF
参考价格
2788.73 *本价格含增值税费
促销
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数量
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产品名称:
328000-16-4
2-Benzyloxyphenylmagnesium bromide solution
2-苄氧基苯基溴化镁 溶液
产品介绍:

产品说明

应用

2-Benzyloxyphenylmagnesium bromide can be used:

  • As a substrate in the iron-catalyzed coupling reaction of aryl Grignard reagents with unprotected bromophenols.
  • As a substrate in the cross-coupling of Grignard reagents using diaryl titanates and ferric chloride.
  • In one of the key synthetic steps for the total synthesis of an antibiotic caboxamycin.

包装

50 mL in Sure/Seal™

基本信息

经验(实验)分子式C13H11BrMgO
分子量287.43
MDL编号MFCD08705262
PubChem化学物质编号24885138

产品性质

质量水平100
reaction suitabilityreaction type: Grignard Reaction
浓度1.0 M in THF
密度1.047 g/mL at 25 ℃
SMILES stringBr[Mg]c1ccccc1OCc2ccccc2
InChI1S/C13H11O.BrH.Mg/c1-3-7-12(8-4-1)11-14-13-9-5-2-6-10-13;;/h1-9H,11H2;1H;/q;;+1/p-1
InChI keyVELKJPFZDYXBDE-UHFFFAOYSA-M

安全信息

象形图GHS02GHS05GHS07GHS08
警示用语:Danger
危险声明H225 - H302 - H314 - H335 - H351
预防措施声明P210 - P260 - P280 - P305 + P351 + P338 - P370 + P378 - P403 + P235
危险分类Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
靶器官Respiratory system
补充剂危害EUH014 - EUH019
储存分类代码3 - Flammable liquids
WGKWGK 3
闪点(F)-4.0 - 5.0 °F - closed cup
闪点(C)-20 - -15 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Sigma-Aldrich

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