<I>cis</I>-1,4-二乙酰氧基-2-丁烯

产品名称：

25260-60-0
cis-1,4-Diacetoxy-2-butene
cis-2-Butene-1,4-diol diacetate
cis-1,4-二乙酰氧基-2-丁烯
顺-1,4-二醋酸基-2-丁烯

产品介绍：

产品说明

一般描述

cis-1,4-Diacetoxy-2-butene is an ester. Ruthenium olefin metathesis catalysts having cyclic (alkyl)(amino)carbenes effectively catalyzes the cross-metathesis of cis-1,4-diacetoxy-2-butene with allylbenzene. cis-1,4-Diacetoxy-2-butene on pyrolysis affords 1-acetoxy-1,3-butadiene, a diacetate and an isomeric 1,2-diacetoxy-3-butene. Mechanism of pyrolysis has been investigated.

应用

cis-1,4-Diacetoxy-2-butene may be used in the preparation of hindered Diels-Alder adducts. It may be used for the synthesis of 1,2,3,4-tetrahydro-2-vinylquinoxalines, via Palladium-catalyzed tandem allylation of 1,2-phenylenediamines.

包装

25 mL in glass bottle

基本信息

线性分子式	CH₃CO₂CH₂CH=CHCH₂O₂CCH₃
分子量	172.18
MDL编号	MFCD00059339
PubChem化学物质编号	24870459
NACRES	NA.22

产品性质

质量水平	100
测定	95%
折射率	n20/D 1.443 (lit.)
bp	120-121 ℃/18 mmHg (lit.)
密度	1.08 g/mL at 25 ℃ (lit.)
SMILES string	[H]\C(COC(C)=O)=C(/[H])COC(C)=O
InChI	1S/C8H12O4/c1-7(9)11-5-3-4-6-12-8(2)10/h3-4H,5-6H2,1-2H3/b4-3-
InChI key	VZUAUHWZIKOMFC-ARJAWSKDSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315
危险分类	Skin Irrit. 2
储存分类代码	10 - Combustible liquids
WGK	WGK 3
闪点(F)	235.4 °F - closed cup
闪点(C)	113 ℃ - closed cup
个人防护装备	Eyeshields, Gloves, type ABEK (EN14387) respirator filter

cis-1,4-Diacetoxy-2-butene

cis-1,4-二乙酰氧基-2-丁烯