产品说明
一般描述
1-Piperidinecarbonitrile in tetrahydrofuran (THF) reacts with a solution of piperidyl lithium in THF at 0℃ to yield lithium[1,1,3,3-bis(pentamethylene)guanidinate]. It participates in thermal decomposition of the 2H-azaphosphirene metal complexes to yield the Δ3-1,3,2-oxazaphospholene complexes and the Δ3-1,3,2-thiazaphospholene complexes.
应用
1-Piperidinecarbonitrile was used in the preparation of 1-selenocarbamoylpiperidine.
Reactant for:
Cycloaddition reactions
Ring-expansion reactions of tungsten complexes
N-CN bond cleavage
Retro-Diels-Alder reactions
Regioselective electrochemical α-methoxylation
Synthesis of de-O-chloroacetylation reagents
包装
5 g in glass bottle
基本信息
| 经验(实验)分子式 | C6H10N2 |
| 分子量 | 110.16 |
| EC 号 | 216-233-8 |
| MDL编号 | MFCD00006477 |
| PubChem化学物质编号 | 24852808 |
| NACRES | NA.22 |
产品性质
| 质量水平 | 100 |
| 测定 | 99% |
| 形式 | liquid |
| 折射率 | n |
| bp | 102 ℃/10 mmHg (lit.) |
| 密度 | 0.951 g/mL at 25 ℃ (lit.) |
| SMILES string | N#CN1CCCCC1 |
| InChI | 1S/C6H10N2/c7-6-8-4-2-1-3-5-8/h1-5H2 |
| InChI key | NVPICXQHSYQKGM-UHFFFAOYSA-N |
安全信息
| 象形图 |  |
| 警示用语： | Warning |
| 危险声明 | H302 + H312 + H332 - H315 - H319 - H335 |
| 预防措施声明 | P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338 |
| 危险分类 | Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
| 靶器官 | Respiratory system |
| 储存分类代码 | 10 - Combustible liquids |
| WGK | WGK 3 |
| 闪点(F) | 206.6 °F - closed cup |
| 闪点(C) | 97 ℃ - closed cup |
| 个人防护装备 | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter |
Sigma-Aldrich
m.cnreagent.com
