产品说明
一般描述
N-(tert-Butoxycarbonyl)-2-bromoaniline, also known as tert-butyl-N-(2-bromophenyl)carbamate, is an N-Boc-protected o-bromoaniline.1 It reacts with ethyl perfluorooctanoate in the presence of tert-butyllithium to form the corresponding 1-hydroxy-1H-perfluorooctyl compound.
应用
N-(tert-Butoxycarbonyl)-2-bromoaniline may be used in the synthesis of N-boc-protected o-aryl anilines, which undergoes coupling reaction with bromoacetylenes to form the corresponding arene?ynamides.
包装
10 g in glass bottle
基本信息
线性分子式 | BrC6H4HNCO2C(CH3)3 |
分子量 | 272.14 |
MDL编号 | MFCD01006614 |
PubChem化学物质编号 | 24877811 |
NACRES | NA.22 |
产品性质
质量水平 | 100 |
测定 | 97% |
折射率 | n |
bp | 110 ℃/0.3 mmHg (lit.) |
密度 | 1.342 g/mL at 25 ℃ (lit.) |
SMILES string | CC(C)(C)OC(=O)Nc1ccccc1Br |
InChI | 1S/C11H14BrNO2/c1-11(2,3)15-10(14)13-9-7-5-4-6-8(9)12/h4-7H,1-3H3,(H,13,14) |
InChI key | UQBGKDLSIIHUEZ-UHFFFAOYSA-N |
安全信息
象形图 | |
警示用语: | Warning |
危险声明 | H315 - H319 - H335 |
预防措施声明 | P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338 |
危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
靶器官 | Respiratory system |
储存分类代码 | 11 - Combustible Solids |
WGK | WGK 3 |
闪点(F) | 230.0 °F - closed cup |
闪点(C) | 110 ℃ - closed cup |
个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
Sigma-Aldrich